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Synthesis of platinum-mercury clusters and the molecular structure of Pt4(HgBr)2(μ-CO)4(PPh3)4

  • Organometallic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

New platinum-mercury clusters, Pt4(HgX)2(μ-CO)4(PR3)4 (X=Cl, Br, I, CF3, or CCl3; R=Ph or Et), were synthesized. The molecular and crystal structure of the Pt4(HgBr)2(μ-CO)4(PPh3)4 cluster was established by X-ray structural analysis.

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Authors and Affiliations

  1. Institute of Carbon Material Chemistry, Siberian Branch of the Russian Academy of Sciences, 18 Sovetsky prosp., 650099, Kemerovo, Russian Federation

    N. K. Eremenko & S. S. Kurasov

  2. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation

    A. V. Virovets

  3. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    T. Struchkov, V. V. Bashilov & V. I. Sokolov

Authors
  1. N. K. Eremenko
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  2. S. S. Kurasov
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  3. A. V. Virovets
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  4. T. Struchkov
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  5. V. V. Bashilov
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  6. V. I. Sokolov
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Additional information

Deceased.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 168–171, January, 1997.

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Eremenko, N.K., Kurasov, S.S., Virovets, A.V. et al. Synthesis of platinum-mercury clusters and the molecular structure of Pt4(HgBr)2(μ-CO)4(PPh3)4 . Russ Chem Bull 46, 164–167 (1997). https://doi.org/10.1007/BF02495367

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  • DOI: https://doi.org/10.1007/BF02495367

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