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30-Electron cationic iron- and cobalt-containing triple-decker complexes with a central cyclopentadienyl ligand. The first synthesis of the parent triple-decker iron complex with cyclopentadienyl ligands, [(η-C5H5)Fe(μ-η:η-C5H5)Fe(η-C5H5)]PF6

  • Organometallic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The parent 30-electron triple-decker iron complex with cyclopentadienyl ligands, [(η-C5H5)Fe(μ-η:η-C5H5)Fe(η-C5H5)]PF6 (1), was prepared for the first time by visible-light irradiation of ferrocene and [(η-C5H5)Fe(η-C6H6)]PF6 in CH2Cl2 at 0 °C. An analogous reaction performed with the use of (η-C5H5)Co(η-C4Me4) (2) instead of ferrocene afforded the thermally labile 30-electron cationic iron-cobalt triple-decker complex [(η-C5H5)Fe(μ-η:η-C5H5)Co(η-C4Me4)]PF6. The latter reacted with compound 2 at 20 °C to form the symmetrical 30-electron cationic dicobalt triple-decker complex [(η-C4Me4)Co(μ-η:η-C5H5)Co(η-C4Me4)] PF6.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    A. R. Kudinov, A. A. Fil'chikov, P. V. Petrovskii & M. I. Rybinskaya

Authors
  1. A. R. Kudinov
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  2. A. A. Fil'chikov
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  3. P. V. Petrovskii
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  4. M. I. Rybinskaya
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya. No. 7, pp. 1364–1367, July, 1999.

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Kudinov, A.R., Fil'chikov, A.A., Petrovskii, P.V. et al. 30-Electron cationic iron- and cobalt-containing triple-decker complexes with a central cyclopentadienyl ligand. The first synthesis of the parent triple-decker iron complex with cyclopentadienyl ligands, [(η-C5H5)Fe(μ-η:η-C5H5)Fe(η-C5H5)]PF6 . Russ Chem Bull 48, 1352–1355 (1999). https://doi.org/10.1007/BF02495303

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  • DOI: https://doi.org/10.1007/BF02495303

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