Abstract
Mercuration and bromination reactions of ferracarborane 3-(η5-Cp)-4-SMe2-3,1,2-FeC2B9H10 (1) were investigated. Mercuration of 1 under mild conditions (mercury trifluoroacetate in dichloromethane) results in 8-monosubstituted mercury derivative as the only reaction product. Depending on the reaction conditions, bromination of 1 results in 8-mono- or 7,8-disubstituted bromo derivatives. The structures of the monomercury and dibromo derivatives of 1 were established by X-ray analysis.
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Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1609–1615, September, 2000.
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Timofeev, S.V., Lobanova, I.A., Kudinov, A.R. et al. Electrophilic substitution reactions of ferracarborane 3-(η5-Cp)-4-SMe2-3,1,2-FeC2B9H10 . Russ Chem Bull 49, 1598–1604 (2000). https://doi.org/10.1007/BF02495166
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DOI: https://doi.org/10.1007/BF02495166