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Synthesis and transformations of metallacycles

21. A novel method for the synthesis of 1,1-dialkylcyclopropanes

  • Organic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

A regioselective method for the synthesis of 1,1-dialkylcyclopropanes was developed. The method is based on the reaction of 2,3-dialkyl-1-ethylalumacyclopent-2-enes with an excess of dialkyl sulfates (Me2SO4 or Et2SO4). A plausible reaction mechanism was suggested.

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References

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Bashkortostan Republic Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation

    U. M. Dzhemilev, A. G. Ibragimov, I. R. Ramazanov, M. P. Luk'yanova, A. Z. Sharipova & L. M. Khalilov

  2. Ufa Research Center, Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation

    U. M. Dzhemilev, A. G. Ibragimov, I. R. Ramazanov, M. P. Luk'yanova, A. Z. Sharipova & L. M. Khalilov

Authors
  1. U. M. Dzhemilev
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  2. A. G. Ibragimov
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  3. I. R. Ramazanov
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  4. M. P. Luk'yanova
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  5. A. Z. Sharipova
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  6. L. M. Khalilov
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Additional information

For Part 20, see Ref. 1.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1092–1095, June, 2000.

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Dzhemilev, U.M., Ibragimov, A.G., Ramazanov, I.R. et al. Synthesis and transformations of metallacycles. Russ Chem Bull 49, 1086–1089 (2000). https://doi.org/10.1007/BF02494899

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  • DOI: https://doi.org/10.1007/BF02494899

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