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Molecular hydrides of samarium and europium LnH2(THF)2 (Ln=Sm or Eu): Synthesis and properties

  • Organometallic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The molecular hydrides Ln11H2(THF)2 (Ln=Sm or Eu) were prepared by hydrogenolysis of the naphthalene complexes of divalent samarium and europium C10H8Ln(THF)2 (Ln=Sm or Eu, respectively) as well as of the stilbene derivative of samarium(II) (PhCHCHPh)Sm(DME)2 in THF at room temperature under atmospheric pressure. The resulting complexes were characterized by the data of microanalysis, IR spectroscopy, and magnetic susceptibility. Chemical properties of the complexes were studied.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhnii Novgorod, Russian Federation

    E. A. Fedorova, A. A. Trifonov, E. N. Kirillov & M. N. Bochkarev

Authors
  1. E. A. Fedorova
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  2. A. A. Trifonov
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  3. E. N. Kirillov
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  4. M. N. Bochkarev
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 947–945, May, 2000.

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Fedorova, E.A., Trifonov, A.A., Kirillov, E.N. et al. Molecular hydrides of samarium and europium LnH2(THF)2 (Ln=Sm or Eu): Synthesis and properties. Russ Chem Bull 49, 946–948 (2000). https://doi.org/10.1007/BF02494723

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  • DOI: https://doi.org/10.1007/BF02494723

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