Abstract
Smil-intermediates generated upon addition of (Me2N)3P to a solution of SmI2 in THF exhibit the properties of a single-electron reducing agent and an N-nucleophile. In particular,N,N-dimethylamides are formed from esters.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 327–329, February, 2000.
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Ivanova, N.A., Shainurova, A.M. & Miftakhov, M.S. Some features of an SmI2−(Me2N)3P—THF system. Transformation of esters into dimethylamides. Russ Chem Bull 49, 329–331 (2000). https://doi.org/10.1007/BF02494683
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DOI: https://doi.org/10.1007/BF02494683