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Effect of γ-substitution on the thermoluminescence properties of terbium (III) acetylacetonate complexes with 1,10-phenanthroline

  • Physical Chemistry
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Abstract

The coordination compounds [Tb(NO3)2 acac(phen)2]H2O (where acac is acetylacetone or its derivatives substituted in the γ-position) were synthesized and studied by luminescence, IR, and UV spectroscopy. Thermoluminescence of the complexes containing acetylacetonate, 3-phenylthio-2,4-pentadioñate, and 3-(p-methoxyphenylthio)-2,4-pentadionate was found. The structural and electronic aspects of the crystal thermoluminescence were discussed.

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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 288–291, February, 2000.

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Karasev, V.E., Mirochnik, A.G., Polyakova, N.V. et al. Effect of γ-substitution on the thermoluminescence properties of terbium (III) acetylacetonate complexes with 1,10-phenanthroline. Russ Chem Bull 49, 291–294 (2000). https://doi.org/10.1007/BF02494674

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  • DOI: https://doi.org/10.1007/BF02494674

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