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Adducts of lanthanide acetylacetonates with 5-phenyl-2-(2-pyridyl)-7,8-benzo-6,5-dihydro-1,3,6-triazaindolizine: structure and photoluminescence

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Abstract

A series of isostructural complexes of the formula Ln(acac)3L (where Hacac is the acetylacetone, L is the 5-phenyl-2-(2-pyridyl)-7,8-benzo-6,5-dihydro-1,3,6-triazaindolizine, Ln are the LaIII, TbIII, EuIII, and SmIII) was studied. Molecular and crystal structures of terbium and samarium complexes were established by X-ray diffraction analysis. Luminescence properties of solid samples were studied. Coordination of 5-phenyl-2-(2-pyridyl)-7,8-benzo-6,5-dihydro-1,3,6-triazaindolizine as an additional ligand increases intensity of photoluminescence. Luminescence spectra of compositions Eu x Tb1−x (acac)3L and La0.6Eu0.1Tb0.3(acac)3L were studied. A combination of several lanthanide ions allowed us to obtain almost white emission.

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Authors and Affiliations

  1. V. I. Vernadsky Tauride National University, 4 prosp. Vernadskogo, 295007, Simferopol’, Republic of Crimea, Russian Federation

    A. N. Gusev & V. F. Shul’gin

  2. Institute for Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163, A-1060, Vienna, Austria

    W. Linert

  3. Department of Chemistry and Biological Science, College of Science and Technology, Aoyama Gakuin University, Kanagawa, 252-5258, Japan

    M. Hasegawa

  4. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    G. G. Aleksandrov & I. L. Eremenko

Authors
  1. A. N. Gusev
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  2. V. F. Shul’gin
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  3. W. Linert
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  4. M. Hasegawa
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  5. G. G. Aleksandrov
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  6. I. L. Eremenko
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Corresponding author

Correspondence to A. N. Gusev.

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Dedicated to Academician of the Russian Academy of Sciences O. N. Chupakhin on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1493–1497, July, 2014.

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Gusev, A.N., Shul’gin, V.F., Linert, W. et al. Adducts of lanthanide acetylacetonates with 5-phenyl-2-(2-pyridyl)-7,8-benzo-6,5-dihydro-1,3,6-triazaindolizine: structure and photoluminescence. Russ Chem Bull 63, 1493–1497 (2014). https://doi.org/10.1007/s11172-014-0625-4

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  • DOI: https://doi.org/10.1007/s11172-014-0625-4

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