Abstract
Regression analysis of the influence of the structure of nonionic organic compounds on their partition coefficients (K gm) between the sodium dodecyl sulfate (SDS) micelles and the gas phase in aqueous micellar SDS solutions was performed using the descriptors characterizing the mechanisms of interaction between these compounds and SDS micelles. For alkanes and compounds with hydroxyl groups, as well as for aromatic and aliphatic compounds without hydroxyl groups, the log(K gm) values are described by separate regression equations, which is due to specific features of intermolecular interactions for these types of organic compounds in the case of their solubilization by SDS micelles.
Similar content being viewed by others
References
K. L. Mittal and P. Mukerjee,Micellization, Solubilization, and Microemulsions, Ed. K. L. Mittal, Plenum Press, New York, 1977,1, 7.
S. Yang and M. G. Khaledi,Anal. Chem., 1995,67, 499.
M. F. Vitha, A. J. Dallas, and P. W. Carr,J. Phys. Chem., 1996,100, 5050.
M. H. Abraham, H. S. Chadha, J. P. Dixon, C. Rafols, and C. Treiner,J. Chem. Soc., Perkin Trans. 2, 1997, 19.
M. H. Abraham, H. S. Chadha, J. P. Dixon, C. Rafols, and C. Treiner,J. Chem. Soc., Perkin Trans. 2, 1995, 887.
F. H. Quina, E. O. Alonso, and J. P. S. Farah,J. Phys. Chem., 1995,99, 11708.
M. H. Abraham,Chem. Soc. Rev., 1993,22, 73.
M. H. Abraham, J. Andonian-Haftman, G. S. Whiting, A. Leo, and R. S. Taft,J. Chem. Soc., Perkin, Trans. 2, 1994, 1777.
D. A. Suslov and B. N. Solomonov,Zh. Fiz. Khim., 1998,72, 938 [Russ. J. Phys. Chem., 1998,72 (Engl. Transl.)].
D. A. Suslov and B. N. Solomonov,Zh. Fiz. Khim., 1993,67, 757 [Russ. J. Phys. Chem., 1993,67 (Engl. Transl.)].
D. A. Suslov, E. G. Yarkova, and B. N. Solomonov,Zh. Fiz. Khim., 1996,70, 736 [Russ. J. Phys. Chem., 1996,70 (Engl. Transl.)].
K. K. Fox, I. D. Robb, and R. Smith,J. Chem. Soc., Faraday Trans. 1, 1972,68, 445.
J. H. Fendler and E. J. Fendler,Catalysis in Micellar and Macromolecular Systems, Academic Press, New York, 1975, 75.
P. Mukerjee, J. R. Cardinal, and N. R. Desai,Micellization, Solubilization, and Microemulsions, Ed. K. L. Mittal, Plenum Press, New York, 1977,1, 241.
Author information
Authors and Affiliations
Additional information
Translated fromIzvestiya Nauk. Seriya Khimicheskaya, No. 2, pp. 248–252, February, 2000.
Rights and permissions
About this article
Cite this article
Bel'skii, V.E. Distribution of nonionic compounds between the gas phase and sodium dodecyl sulfate micelles. Russ Chem Bull 49, 251–255 (2000). https://doi.org/10.1007/BF02494666
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02494666