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Interactions of aliphatic β-amino-β-trifluoromethylvinyl ketones with ethylenediamine

  • Organic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The reactions of aliphatic β-amino-β-trifluoromethylvinyl ketones with an excess of ethylenediamine at room temperature afforded the corresponding 2,3-dihydro-1H-1,4-diazepines or substituted 2-acetonyl-2-trifluoromethylimidazolidines (the latter were obtained when the approach to the carbonyl group was sterically hindered).

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References

  1. K. I. Pashkevich, A. Ya. Aizikovich, and I. Ya. Postovskii,Izv. Akad. Nauk SSSR, Ser. Khim. 1981, 455 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1981,30 (Engl. Transl.)].

    Google Scholar 

  2. G. M. J. Slusarczuk and M. M. JoullieJ. Org. Chem., 1971,36, 37.

    Article  Google Scholar 

  3. V. Ya. Sosnovskikh and M. Yu. Mel'nikov,Mendeleev Commun., 1998, 19.

  4. H. W. Wanzlick and W. Lochel,Chem. Ber., 1953,86, 1463.

    Article  CAS  Google Scholar 

  5. T. H. Fife and J. E. C. Hutchins,J. Am. Chem. Soc., 1976,98, 2536.

    Article  CAS  Google Scholar 

  6. V. Ya. Sosnovskikh and M. Yu. Mel'nikov,Zh. Org. Khim., 1998,34, 303 [Russ. J. Org. Chem., 1998,34 (Engl. Transl.)].

    Google Scholar 

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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2305–2308, November, 1998.

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Sosnovskikh, V.Y., Mel'nikov, M.Y. & Kovaleva, I.A. Interactions of aliphatic β-amino-β-trifluoromethylvinyl ketones with ethylenediamine. Russ Chem Bull 47, 2234–2237 (1998). https://doi.org/10.1007/BF02494288

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  • DOI: https://doi.org/10.1007/BF02494288

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