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209Bi NQR study of bismuth(III) complexes

  • Physical Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Potassium pentafluorobismuthate(III), nitrate-chloride BiIII complexes MBiCl3NO3 (M=K, (NH2)2CNH2), sulfate-chloride BiIII complexes MBiCl2SO4 (M=K, Rb, NH4, (NH2(2CNH2), and BiIII complexonates with the anions of ethylenediaminetetraacetic acid M[Bi(edta)]2·nH2O (M=Mg, Ca, Ni, Cd) and nitrilotriacetic acid Bi(nta)·2H2O, and Bi(nta)·3thio·H2O (thio is thiourea) were studied by209Bi NQR spectroscopy. A second-order phase transition was observed in K2BiF5 at 100 K. The compounds Bi(nta)·2H2O, (NH2)2CNH2BiCl3NO3, and MBiCl2SO4 (M=K, NH4) are piezoelectrics.

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References

  1. G. K. Semin, T. A. Babushkina, and G. G. Yakobson,Nuclear Quadrupole Resonance in Chemistry, Keter Publishing House, Ltd., Jerusalem; J. Wiley and Sons, New York, 1975, 517 pp.

    Google Scholar 

  2. Author's Certificate USSR No. 1386751, 1987 (in Russian).

  3. R. L. Davidovich, M. A. Medkov, E. B. Irkhina, and L. V. Teplukhina,Izv. Akad. Nauk SSSR, Ser. Khim., 1986,35, 1325 (Engl. Transl.)].

  4. R. L. Davidovich, M. A. Medkov, E. B. Bogomolova, and L. A. Zemnukhova,Izv. Akad. Nauk SSSR, Ser. Khim., 1984, 973 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1984,33, 895 (Engl. Transl.)].

    Google Scholar 

  5. A. A. Loginov, M. A. Medkov, V. E. Karasey, and R. L. Davidovich,Ukr. Khim. Zh. [Ukr. Chem. Bull.], 1989,55, 1134 (in Russian).

    CAS  Google Scholar 

  6. A. A. Loginov, M. A. Medkov, V. E. Karasev, and R. L. Davidovich,Ukr. Khim. Zh. [Ukr. Chem. Bull.], 1989,55, 795 (in Russian).

    Google Scholar 

  7. G. K. Semin, I. M. Alymov, V. M. Burbello, V. A. Egorov, A. A. Boguslavskii, and R. Sh. Lotfullin,Izv. Akad. Nauk SSSR. Ser. Fiz., 1975,39, 2607 [Bull. Acad. Sci. USSR. Phys. Ser., 1975,39, 135 (Engl. Transl.)].

    CAS  Google Scholar 

  8. L. A. Zemnukhova, R. L. Davidovich, P. S. Gordienko, J. Grigas, A. N. Kovrianov, S. I. Kuznetsov, T. A. Kaidalova, and V. Urbonavicius,Phys. Stat. Sol. (a), 1983,80, 553.

    CAS  Google Scholar 

  9. T. Kushida, G. B. Benedek, and N. Bloembergen,Phys. Rev., 1956,104, 1364.

    Article  CAS  Google Scholar 

  10. A. A. Udovenko, M. F. Eiberrnan, S. B. Ivanov, A. N. Levin, and S. S. Sergienko,Kristallografiya, 1992,37, 729 [Sov. Phys. Crystallogr., 1992,37 (Engl. Transl.)].

    CAS  Google Scholar 

  11. A. A. Udovenko and R. L. Davidovich,Koord. Khim., 1991,17, 1354 [Sov. J. Coord. Chem., 1991,17 (Engl. Trans.)].

    CAS  Google Scholar 

  12. S. C. Nyburg, G. A. Ozin, and J. T. Szymanski,Acta Crystallogr., 1971,27B, 2298.

    Google Scholar 

  13. M. Bourgault, B. Ducourant, D. Mascherpa-Corral, and R. Fourcade,J. Fluor. Chem., 1981,17, 215.

    Article  CAS  Google Scholar 

  14. H. G. Robinson,Phys. Rev., 1955,100, 1731.

    Article  CAS  Google Scholar 

  15. L. M. Volkova, A. A. Udovenko, A. N. Levin, R. L. Davidovich, and M. A. Medkov,Koord. Khim., 1985,11, 689 [Sov. J. Coord. Chem., 1985,11 (Engl. Transl.)].

    CAS  Google Scholar 

  16. R. Fourcade, M. Bourgault, B. Bonnet, and B. Ducourant,J. Solid. State Chem., 1982,43, 81.

    Article  CAS  Google Scholar 

  17. L. A. Zemnukhova, R. L. Davidovich, S. I. Kuznetsov, and V. N. Rykovanov,Izv, Akad. Nauk SSSR, Ser. Khim., 1987, 1956 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1987,36, 1812 (Engl. Transl.)].

    Google Scholar 

  18. L. A. Zemnukhova, R.L. Davidovich, V. N. Rykovanov, and N. M. Dyatlova,Izv. Akad. Nauk SSSR, Ser. Khim., 1989, 1915 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1989,38, 1961 (Engl. Transl.)].

  19. S. A. Shchukarev,Neorganicheskaya khimiya [Inorganic Chemistry], Vysshaya Shkola, Moscow, 1970 (in Russian).

    Google Scholar 

  20. R. L. Davidovich and Yu. A. Buslaev,Koord. Khim., 1988,14, 1011 [Sov. J. Coord. Chem., 1988,14 (Engl. Transl.)].

    CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Chemistry, Far-Eastern Branch of the Russian Academy of Sciences, 159 prosp. 100-letiya Vladivostoka, 690022, Vladivostok, Russian Federation

    L. A. Zemnukhova & R. L. Davidovich

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    S. I. Kuznetsov

Authors
  1. L. A. Zemnukhova
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  2. S. I. Kuznetsov
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  3. R. L. Davidovich
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2237–2240, November, 1998.

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Zemnukhova, L.A., Kuznetsov, S.I. & Davidovich, R.L. 209Bi NQR study of bismuth(III) complexes. Russ Chem Bull 47, 2169–2172 (1998). https://doi.org/10.1007/BF02494274

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  • DOI: https://doi.org/10.1007/BF02494274

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