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Observations on the effect of temperature on performance and stability of anion exchange columns in ion chromatography

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Summary

The influence of column temperature on elution behaviour of several ions on anion-exchange resin beds of the Dionex Ion Pac type was investigated. Iodate, bromate, bromide and iodide ions were separated on Ion Pac AS9SC column in the temperature range of 10°C–55°C, using NaHCO3/Na2CO3 and NaHCO3 eluents. Free energy, enthalpy and entropy changes for respective ion exchange reactions were calculated and compared with literature data for classical gel type exchangers. In most cases the enthalpy change was a function of temperature. The work at elevated temperatures caused progressing resin degradation i.e. loss of strongly basic groups, accompanied by formation of weakly basic groups and also some weakly acidic groups. Similar resin degradation was observed for Ion Pac AS5 column. Observations on the changes of the plate height with the retention factor and temperature lead to conclusion that in some circumstances longitudinal diffusion in the resin phase also contributes to the total plate height.

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References

  1. Dybczyński, R.Anal. Chim. Acta 1963,29, 369–372.

    Article  Google Scholar 

  2. Dybczyński, R.J. Chromatogr. 1964,14, 79–96.

    Article  Google Scholar 

  3. Dybczyński, R.J. Chromatogr. 1967,13, 155–170.

    Article  Google Scholar 

  4. Wódkiewicz, L.; Dybczyński, R.Chem. Anal. (Warsaw) 1969,14, 437–446.

    Google Scholar 

  5. Dybczyński, R.; Maleszewska, H.Analyst 1969,94, 527–537.

    Article  Google Scholar 

  6. Dybczyński, R.J. Chromatogr. 1972,71, 507–522.

    Article  Google Scholar 

  7. Dybczyński, R.; Maleszewska, H.J. Radioanal. Chem. 1974,21, 229–245.

    Google Scholar 

  8. Wódkiewicz, L.; Dybczyński, R.Chem. Anal. (Warsaw) 1981,26, 419–421.

    Google Scholar 

  9. Baba, Y.; Yoza, N.; Ohashi, S.J. Chromatogr. 1985,348, 27–37.

    Article  CAS  Google Scholar 

  10. Hamilton, P.B.; Bogue, D.C.; Anderson, R.A.Anal. Chem. 1960,32, 1782–1792.

    Article  CAS  Google Scholar 

  11. Dybczyński, R.; Sterliński, S.Chem. Anal. (Warsaw) 1972,17, 1275–1289.

    Google Scholar 

  12. Fołdzinska, A.; Dybczyński, R.J. Radioanal. Chem. 1974,21, 507–517.

    Google Scholar 

  13. Dybczyński, R.; Danko, B.; Maleszewska, H.Zh. Analit. Khim. 1994,49, 37–44;J. Anal. Chem. (Moscow),1994,49, 31–38.

    Google Scholar 

  14. Gjerde, D.T.; Fritz, J.S.Ion Chromatography, Hüthig Verlag, Heidelberg,1987.

    Google Scholar 

  15. Small, H.Ion Chromatography, Plenum Press, New York,1989.

    Google Scholar 

  16. Haddad, P.R.; Jackson, P.E.Ion Chromatography: Principles and Applications. (J. Chromatography Library, vol. 46), Elsevier, Amsterdam,1990.

    Google Scholar 

  17. Weiss, J.Ion Chromatography, 2nd Ed. VCH, Weinheim,1995.

    Google Scholar 

  18. Henderson, D.E.; O'Connor, D.J.Adv. Chromatogr. 1984,23, 65–95.

    CAS  Google Scholar 

  19. Terweij-Groen, C.P.; Kraak, J.C.J. Chromatogr. 1977,138, 245–266.

    Article  CAS  Google Scholar 

  20. Gennaro, M.C.; Giacosa, D.; Abrigo, C.; Marengo, E.J. Chromatogr. Sci. 1995,33, 360–364.

    CAS  Google Scholar 

  21. Pecina, R.; Bonn, G.; Burtscher, E.; Bobleter, O.J. Chromatogr. 1984,287, 245–258.

    Article  CAS  Google Scholar 

  22. Wolcott, R.G.; Dolan, J.W.LC-GC Int. 1999,12 (1), 14–18.

    Google Scholar 

  23. Snyder, L.R.J. Chromatogr. B 1997,689, 105–115.

    CAS  Google Scholar 

  24. Dolan, J.W.; Snyder, L.R.; Blanc, T.; Van Heukelem, L.J. Chromatogr. A 2000,897, 37–50.

    Article  CAS  Google Scholar 

  25. Dolan, J.W.; Snyder, L.R.; Blanc, T.J. Chromatogr. A 2000,897, 51–63.

    Article  CAS  Google Scholar 

  26. Yan, B.; Zhao, J.; Brown, J.S.; Blackwell, J.; Carr, P.W.Anal. Chem. 2000,72, 1253–1262.

    Article  CAS  Google Scholar 

  27. Ranatunga, R.P.J.; Carr, P.W.Anal. Chem. 2000,72, 5679–5692.

    Article  CAS  Google Scholar 

  28. Głód, B.K.; Alexander, P.W.; Chen, Zu.L.; Haddad, P.R.Anal. Chim. Acta 1995,306, 267–272.

    Article  Google Scholar 

  29. Rey, M.A.; Pohl, C.A.J. Chromatogr. A 1996,739, 87–97.

    Article  CAS  Google Scholar 

  30. Pohl, C.A.; Stillian, J.R.; Jackson, P.E.J. Chromatogr. A 1997,789, 29–41.

    Article  CAS  Google Scholar 

  31. Haidekker, A.; Huber, C.G.J. Chromatogr. A 2001,921, 217–226.

    Article  CAS  Google Scholar 

  32. Bashir, W.; Paull, B.J. Chromatogr. A 2002,942, 73–82.

    Article  CAS  Google Scholar 

  33. Rey, M.A.J. Chromatogr. A 2001,920, 61–68.

    Article  CAS  Google Scholar 

  34. Hatsis, P.; Lucy, C.L.Analyst,2001,126, 2113–2121.

    Article  CAS  Google Scholar 

  35. Pirogov, A.V.; Obrezkov, O.N.; Shpigun, O.A.Zh. Anal. Khim. 1997,52, 172–176.

    Google Scholar 

  36. Smith, R.G.; Drake, P.A.; Lamb, J.D.J. Chromatogr. 1991,546, 139–149.

    Article  CAS  Google Scholar 

  37. Hatsis, P.; Lucy, C.L.J. Chromatogr. A 2001,920, 3–11.

    Article  CAS  Google Scholar 

  38. AI-450 Chromatography User's Guide, Doc. No 034039, Release 09, March1993.

  39. Minczewski, J.; Chwastowska, J.; Dybczyński, R.Separation and Preconcentration Methods in Inorganic Trace Analysis, Horwood, Chichester,1982.

    Google Scholar 

  40. Dolan, J.W.LC-GC Europe 2002,15, 394–397.

    CAS  Google Scholar 

  41. Bonner, O.D.J. Phys. Chem. 1954,58, 318–322.

    Article  CAS  Google Scholar 

  42. Kraus, K.A.; Raridon, R.J.J. Phys. Chem. 1959,63, 1901–1907.

    Article  CAS  Google Scholar 

  43. Dybczyński, R.; Wódkiewicz, L.J. Inorg. Nucl. Chem. 1969,31, 1495–1506.

    Article  Google Scholar 

  44. Kraus, K.A.; Raridon, R.J.; Holcomb, D.L.J. Chromatogr. 1960,3, 178–189.

    Article  CAS  Google Scholar 

  45. Polkowska-Motrenko, H.; Kulisa, K.; Dybczyński, R.Chem. Anal. (Warsaw) 1998,43, 365–373.

    CAS  Google Scholar 

  46. Ravindranath, B.Principles and Practice of Chromatography, Horwood, Chichester,1989.

    Google Scholar 

  47. Neue, U.D.HPLC columns. Theory, Technology, and Practice, Wiley-VCH, New York,1997.

    Google Scholar 

  48. Ahuja, S.Trace and ultratrace analysis by HPLC, Wiley, New York,1992.

    Google Scholar 

  49. Snyder, L.R.; Kirkland, J.J.; Glajch, J.L.Practical HPLC method development, Wiley, New York,1997.

    Google Scholar 

  50. Glueckauf, E.Ion Exchange and its Applications, Society of Chemical Industry, London,1955, p. 34.

    Google Scholar 

  51. Dybczyński, R.J. Chromatogr. 1970,50, 487–503.

    Article  Google Scholar 

  52. Giddings, J.C.Dynamics of Chromatography, Part I, Dekker, New York,1965.

    Google Scholar 

  53. Wódkiewicz, L.; Dybczyński, R.J. Chromatogr. 1972,68, 131–141.

    Article  Google Scholar 

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  1. Department of Analytical Chemistry, Institute of Nuclear Chemistry and Technology, Dorodna 16str, 03-195, Warszawa, Poland

    R. Dybczyński & K. Kulisa

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  1. R. Dybczyński
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  2. K. Kulisa
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Dybczyński, R., Kulisa, K. Observations on the effect of temperature on performance and stability of anion exchange columns in ion chromatography. Chromatographia 57, 475–484 (2003). https://doi.org/10.1007/BF02492544

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  • DOI: https://doi.org/10.1007/BF02492544

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