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Chromatographic separation of asymmetric organosilicon compounds on cellulose and amylose stationary phases. The stereochemistry of functional transformation reactions

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Summary

Silicon compounds, especially silanes, have been separated on cellulose carbamate and amylose carbamate stationary phases. Reasonable recognition is achieved in the separation of organosilicon compounds on cellulose carbamate. Stereoselectivity at the asymmetric silicon center in functional transformation reactions is discussed.

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Shinke, S., Kawakami, Y. Chromatographic separation of asymmetric organosilicon compounds on cellulose and amylose stationary phases. The stereochemistry of functional transformation reactions. Chromatographia 53, 140–146 (2000). https://doi.org/10.1007/BF02491561

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  • DOI: https://doi.org/10.1007/BF02491561

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