Skip to main content
SpringerLink
Log in

A survey of the potential of the high performance liquid chromatography and capillary zone electrophoresis for the determination of platinum and platinum group metals

  • Reviews
  • Published:
Chromatographia Aims and scope Submit manuscript

Summary

Various platinum group metals (PGMs) can be separated in the form of complexes with monodentate ligands, ion associates or chelates by high performance liquid chromatography (HPLC) or capillary zone electrophoresis (CZE). Ion associates of anionic monodentate PGM complexes with low and high-molecular-mass ammonium cations give satisfactory results in ion interaction HPLC on reversed phase silica in the presence of CH3CN or CH3OH modifiers. PGM chelates often show considerable shortcomings due to kinetic hindrance during their formation and must be formed prior to HPLC application. Capillary zone electrophoresis (CZE) brings some new aspects to the separation of PGMs in addition to increasing separation speed and miniaturization of the system. Both methods can be successfully used for the treatment of platinum anti-cancer drugs, their organic impurities, hydrolytic products or metabolites in body fluids. Representative examples are discussed in this paper.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Biu Qu, Y.Analyst 1996,121, 139–161.

    Article  Google Scholar 

  2. Balcerzak, M.Analyst 1997,122, 67R-74R.

    Article  CAS  Google Scholar 

  3. Pyrzynska, K.Talanta 1998,47, 841–848.

    Article  CAS  Google Scholar 

  4. Vlašánková, R.; Sommer, L.Chem. Pap. 1999,53, 200–209.

    Google Scholar 

  5. Ginzburg, S.I.; Yezerskaya, N.A. and EditorsAnaliticheskaya Khimia Platinovych Metallov, Nauka, Moskva,1972, p. 45–132.

    Google Scholar 

  6. Smith, R.M.; Martell, A.E.Critical Stability Constants, 4, Plenum Press, New York,1976, p. 107.

    Google Scholar 

  7. Stability Constants of Metal- Ion Complexes, Part A, Inorganic Ligands (compiled by E. Hoegfeldt), Pergamon Press, Oxford,1982.

  8. Timerbaev, A.R.; Petrukhin, O.M.; Orlov, V.I.; Aratskova, A.A.J. Liq. Chromatogr. 1992,15, 1443–1461.

    CAS  Google Scholar 

  9. Timerbaev, A.R.; Petrukhin, O.M.,Zh. Anal. Khim 1991,46, 213–224.

    CAS  Google Scholar 

  10. Timerbaev, A.R.; Petrukhin, O.M.; Alimarin, I.P.; Bol'shova, T.A.Talanta 1991,38, 467–476.

    Article  CAS  Google Scholar 

  11. Huang, Q.; Paull, B.; Haddad, P.R.J. Chromatogr. 1997,A770, 3–11.

    Article  Google Scholar 

  12. Alimarin, I.P.; Ivanov, V.M.; Bol'shova, T.A.; Basova, E.M.Fresenius' J. Anal. Chem. 1989,335, 63–69.

    Article  CAS  Google Scholar 

  13. Alimarin, I.P.; Basova, E.M.; Bol'shova, T.A.; Ivanov, V.M.Zh. Anal. Khim. 1986,41, 5–34.

    CAS  Google Scholar 

  14. Havel, J.; Khramov, A.N.Scr. Fac. Sci. Nat Univ. Mas. Brun. (Chemia) 1997–98, 27–28, 51–62.

    Google Scholar 

  15. Basova, E.M.; Bol'shova, T.A.; Shpigun, O.A.; Ivanov, V.M.Zh. Anal. Khim. 1993,48, 1094–1115.

    CAS  Google Scholar 

  16. Doležal, J.; Sommer, L.Coll. Czech. Chem. Commun. 1997,62, 1029–1042.

    Article  Google Scholar 

  17. Doležal, J.; Štepán, M.; Sommer, L.International Congress on Analytical Chemistry, Moscow, Russia, June 15–21,1997, Book of Abstracts, Abstract E-29.

  18. Vlašánková, R.; Otruba, V.; Bendl, J.; Fišera, M.; Kanický, V.Talanta 1999,48, 839–846.

    Article  Google Scholar 

  19. Bidlingmeyer, B.A.J. Chromatogr. Sci. 1980,18, 525–530.

    CAS  Google Scholar 

  20. Hayakawa, K.; Nishijima, M.; Miyazaki, M.Bunseki Kagaku 1982,31, 160–161,Anal. Abstr. 1982,43, 4B186.

    CAS  Google Scholar 

  21. Hayakawa, K.; Takizawa, T.; Furuta, M.; Miyazaki, M.Bunseki Kagaku 1983,32, E243-E250.Anal. Abstr. 1984,46, 4B181.

    CAS  Google Scholar 

  22. Haddad, P.R.; Rochester, N.E.Anal. Chem. 1986,60, 536–540.

    Article  Google Scholar 

  23. Hilton, D.F.; Haddad, P.R.J. Chromatogr. 1986,361, 141–150.

    Article  CAS  Google Scholar 

  24. Rochester, N.E.; Haddad, P.R.Chem. Austr. 1987,54 164.

    CAS  Google Scholar 

  25. Khramov, A.N.; Havel, J.Scr. Fac. Sci. Nat. Univ. Mas. Brun. (Chemia) 1997–98, 27–28, 63–73.

    Google Scholar 

  26. Mojski, M.; Gluch, I.; Obarski, N.Chem. Anal. (Warsaw) 1997,42, 825–835.

    CAS  Google Scholar 

  27. Steinbrech, B.; Schneeweiss, G.; Koenig, K.H.Fresenius' J. Anal. Chem. 1982,311, 499–502.

    CAS  Google Scholar 

  28. Nachtigall, D.; Artelt, S.; Wuensch, G.J. Chromatogr. A 1997,775, 197–210.

    Article  CAS  Google Scholar 

  29. Vláčil, F.; Vinš, I.; Malícek, O.Coll. Czech. Chem. Commun. 1983,48, 2255–2262.

    Google Scholar 

  30. Timerbaev, A.R.; Tsoi, I.G.; Petrukhin, O.M.;J. Chromatogr. 1990,498, 337–348.

    Article  CAS  Google Scholar 

  31. Bol'shova, T.A.; Nesterenko, P.N.; Basova, E.M.; Morozova, N.B.; Ivanov, V.M.Zh. Anal. Khim. 1987,42, 1648–1654.

    Google Scholar 

  32. Doležal, J.; Sommer, L.Coll. Czech. Chem. Commun. 1994,59, 2209–2226.

    Article  Google Scholar 

  33. Ohtsuka, C.; Matsukawa, K.; Wada, H.; Nagakawa, G.Anal. Chim. Acta 1992,256, 91–96.

    Article  CAS  Google Scholar 

  34. Sommer, L.; Doležal, J.Scr. Fac. Sci. Nat. Univ. Mas. Brun. (Chemia) 1996,26, 65–92.

    CAS  Google Scholar 

  35. Voštová, J.; Sommer, L.Coll. Czech. Chem. Commun. 1976,41, 1137–1168.

    Google Scholar 

  36. Yotsuyanagi, T.; Hoshino, H.; Aomura, K.Anal. Chim. Acta. 1974,71, 349–354.

    Article  CAS  Google Scholar 

  37. Ivanov, V.M.; Gorbunova, G.N.Zh. Anal. Khim. 1980,35, 2363–2368.

    CAS  Google Scholar 

  38. Gorbunova, G.N.; Ivanov, V.M.Zh. Anal. Khim. 1980,35, 705–712.

    CAS  Google Scholar 

  39. Gorbunova, G.N.; Ivanov, V.M.Zh. Anal. Khim. 1982,37, 880–886.

    CAS  Google Scholar 

  40. Basova, E.M.; Bol'shova, T.A.; Ivanov, V.M.; Morozova, N.B.Zh. Anal. Khim. 1989,44, 680–688.

    CAS  Google Scholar 

  41. Nikitin, Yu.S.; Morozova, N.B.; Lanin, S.N.; Bol'shova, T.A.; Ivanov, V.M.; Basova, E.M.;Talanta 1987,34, 223–226.

    Article  CAS  Google Scholar 

  42. Basova, E.M.; Ivanov, V.M.; Morozova, N.B.Zh. Anal. Khim. 1990,45, 671–678.

    CAS  Google Scholar 

  43. Alimarin, I.P.; Nikitin, Yu.S.; Ivanov, V.M.; Bolśkava, T.A.; Basova, E.M.Dokl. Akad. Nauk 1986,288, 1112–1115.

    CAS  Google Scholar 

  44. Bol'shova, T.A.; Nesterenko, P.N.; Basova, E.M.; Ivanov, V.M.Zh. Anal. Khim. 1987,42, 1648–1654.

    Google Scholar 

  45. Uehara, N.; Annoh, Y.; Shimono, T.; Shijo, Y.Anal. Sci. 1989,5, 111–112.

    CAS  Google Scholar 

  46. Mueller, B.J.; Lovett, R.J.Anal Chem. 1987,59, 1405–1409.

    Article  CAS  Google Scholar 

  47. Mueller, B.J.; Lovett, R.J.Anal. Chem. 1985,57, 2693–2699.

    Article  CAS  Google Scholar 

  48. Alimarin, I.P.; Basova, E.M.; Mishenina, T.V.; Bol'shova, T.A.; Shpigun, O.A.Talanta 1990,37, 485–489.

    Article  CAS  Google Scholar 

  49. Wenclawiak, B.; Bickmann, F.Bunseki Kagaku 1984,33, E67-E72 (1984).Anal. Abstr 1984,46, 10B163.

    CAS  Google Scholar 

  50. Basova, E.M.; Bondareva, L.G.; Ivanov, V.M.Zh. Anal. Khim. 1992,47, 1712–1719.

    CAS  Google Scholar 

  51. Basova, E.M.; Ivanov, V.M.; Bondareva, L.G.;Zh. Anal. Khim. 1996,51, 954–960.

    Google Scholar 

  52. Basova, E.M.; Bondareva, L.G.; Ivanov, V.M.;Zh. Anal. Khim. (Moscow) 1997,52, 36–42.

    Google Scholar 

  53. Marsh, K.C.; Sternson, L.A.; Repta, A.J.Anal. Chem. 1984,56, 491–497.

    Article  CAS  Google Scholar 

  54. Gurira, N.; Carr, P.W.J. Chromatogr. Sci. 1982,20, 461–465.

    CAS  Google Scholar 

  55. Li, L.; Li, D.Sepn. 1990,8, 177–179.Anal. Abstr. 1991,53, 7D76.

    CAS  Google Scholar 

  56. Steinbrech, B.; Koenig, K.H.Fresenius' J. Anal. Chem. 1983,316, 685–688.

    Article  CAS  Google Scholar 

  57. Koenig, K.H.; Ehmcke, H.V.; Schneeweiss, G.; Steinbrech, B.Fresenius' J. Anal. Chem. 1979,297, 411–413.

    Article  CAS  Google Scholar 

  58. Khuhawar, M.Y.; Soomro, A.Anal. Chim. Acta 1992,268, 49–53.

    Article  CAS  Google Scholar 

  59. Prudnikov, G.K.; Garifzyanov, A.R.; Savel'eva, A.N.; Al-Hatib, D.Zh. Anal. Khim. 1992,47, 1999–2003.

    Google Scholar 

  60. Caroli, S.; Alimonti, A.; Petrucci, F.; La Torre, F.; Dominici, C.; Castello, M.A.Ann. Inst. Super. Sanita 1989,25, 487–498.

    CAS  Google Scholar 

  61. Cairns, W.R.L.; Ebdon, L.; Hill, C.J.Anal. Proc. 1994,31, 295–297.

    CAS  Google Scholar 

  62. Kizu, R.; Kaneda, M.; Miyazaki, M.Anal. Sci. 1992,8, 145–150.

    CAS  Google Scholar 

  63. Krull, I.S.; Ding, X.D.; Braverman, S.; Selavka, C.; Hochberg, F.; Sternson, L.A.J.Chromatogr. Sci. 1983,21, 166–173.

    CAS  Google Scholar 

  64. Abrams, M.J.; Murrer, B.A.Science 1993,261, 725–730.

    CAS  Google Scholar 

  65. Kelland, L.R.; Clarke, S.J.; McKlage, M.J.Platinum Met. Rev. 1992,36, 178.

    CAS  Google Scholar 

  66. Nuttal, K.L.; Gordon, W.H.; Oven, K.A.Clin. Chem. 1994,40, 1787.

    Google Scholar 

  67. Riley Ch.M.; Sternson, L.A.; Repta, A.J.; Slyter, S.A.Anal. Biochem. 1983,130, 203–214.

    Article  CAS  Google Scholar 

  68. Macka, M.; Borák, J.; Kiss, F.J. Chromatogr. 1991,586, 291–295.

    Article  CAS  Google Scholar 

  69. Parsons, P.J.; Morisson, P.F.; LeRoy, A.F.J. Chromatogr. 1987,385, 323–335.

    Article  CAS  Google Scholar 

  70. de Waal, W.A.J.; Maessen, F.J.M.; Kraak, J.C.J. Chromatogr. 1987,407, 253–272.

    Article  Google Scholar 

  71. Ivanov, A.V.; Zheligovskaya, N.N.; Nesterenko, P.N.Zh. Anal. Khim. 1995,50, 190–195.

    Google Scholar 

  72. Burdakov, V.I.; Miteva, I.M.Dokl. Bolg. Akad. Nauk 1986,39, 61–64.

    Google Scholar 

  73. Macka, M.; Borák, J.J. Chromatogr. 1993,641, 101–113.

    Article  CAS  Google Scholar 

  74. Branšteterová, E.; Kiss, F.; Miertuš, S.; Garaj, J.Mikrochim. Acta 1990,III, 11–19.

    Article  Google Scholar 

  75. Ivanov, A.V.; Kitiashvili, K.D. Ivanov, V.M. Vest. Moskovsk. Univ., Ser. 2Khimia No 2,1998,39, 109–111.

    CAS  Google Scholar 

  76. Dominici, C.; Alimonti, A.; Caroli, S.; Petrucci, F.; Castello, M.A.Clin. Chim. Acta 1986,158, 207–215.

    Article  CAS  Google Scholar 

  77. Riley, G.M.; Sternson, L.A.; Repta, A.J.; Siegler, R.W.J. Chromatogr. 1982,229, 373–386.

    CAS  Google Scholar 

  78. Hansen, S.H.J. Chromatogr. 1989,491, 175–185.

    CAS  Google Scholar 

  79. Baldew, G.S.; Volkers, K.J.; deGoeij, J.J.M.; Vermeulen, N.P.E.J. Chromatogr. 1989,491, 163–174.

    CAS  Google Scholar 

  80. Baraj, B.; Sastre, A.; Martinez, M.; Spahiu, K.Anal. Chim. Acta 1996,319, 191–197.

    Article  CAS  Google Scholar 

  81. Zhang, W.H.; Li, J.; Hu, Z.D.J. Chromatogr. A 1995,707, 242–246.

    Article  Google Scholar 

  82. Pirogov, A.V.; Havel, J.J. Chromatogr. A 1997,772, 347–355.

    Article  CAS  Google Scholar 

  83. Thornton, M.J.; Fritz, J.S.J. Chromatogr. A 1997,770, 301–310.

    Article  CAS  Google Scholar 

  84. Hamáček, J.; Havel, J.J. Chromatogr. A 1999,834, 321–327.

    Article  Google Scholar 

  85. Buchberger, W.; Semenova, O.P.; Timerbaev, A.R.J. High Resol. Chromatogr. 1993,6, 153–156.

    Article  Google Scholar 

  86. Buchberger, W.; Haddad, P.R.J. Chromatogr. A 1994,687, 343–349.

    Article  CAS  Google Scholar 

  87. Kubáñ, P.; Buchberger, W.; Haddad, P.R.J. Chromatogr. A 1997,770, 329–336.

    Article  Google Scholar 

  88. Aquilar, M.; Farran, A.; Marti, V.J. Chromatogr. A 1997,778, 397–402.

    Article  Google Scholar 

  89. Michalke, B.; Lustig, S.; Schramel P.Electrophoresis 1997,18, 196–201.

    Article  CAS  Google Scholar 

  90. Michalke, B.; Schramel, P.Fresenius' J. Anal. Chem. 1997,357, 594–599.

    Article  CAS  Google Scholar 

  91. Lustig, S.; Michalke, B.; Beck, W.; Schramel, P.Fresenius' J. Anal. Chem. 1998,360, 18–25.

    Article  CAS  Google Scholar 

  92. Wenclawiak, B.W.; Wollman, M.J. Chromatogr. A 1996,724, 317–326.

    Article  CAS  Google Scholar 

  93. Watanabe, E.; Nakajima, H.; Bina, E.; Hoshino, H.; Yotsuyanagi, T.Bunseki Kagaku 1983,32, 469–474.Anal. Abstr. 1984,46, 4B190.

    CAS  Google Scholar 

  94. Zhang, H.S.; Mon, W.Y.; Cheng, J.K.Talanta 1994,41, 1459–1463.

    Article  CAS  Google Scholar 

  95. Beketova, N.A.; Basova, E.M.; Ivanov, V.M.; Bol'shova, T.A.Zh. Anal. Khim. 1990,45, 2178–2185.

    CAS  Google Scholar 

  96. Basova, E.M.; Bol'shova, T.A.; Shpigun, O.A.Zh. Anal. Khim. 1993,48, 284–296.

    CAS  Google Scholar 

  97. Basova, E.M.; Bol'shova, T.A.; Shpigun, O.A.Zh. Anal. Khim. 1991,46, 2362–2369.

    CAS  Google Scholar 

  98. Basova, E.M.; Bol'shova, T.A.; Shapovalova, E.N.; Ivanov, V.M.Zh. Anal. Khim. 1990,45, 1947–1954.

    CAS  Google Scholar 

  99. Liu, Q.; Zhang, H.; Cheng, J.Talanta 1991,38, 669–672.

    Article  CAS  Google Scholar 

  100. Shapovalova, E.N.; Mishenina, I.V.; Basova, E.M.; Bol'shova, T.A.; Shpigun, O.A.Zh. Anal. Khim. 1991,46, 1503–1511.

    CAS  Google Scholar 

  101. Liu, Q.P.; Zhao, T.; Liu, J.C.; Cheng, J.K.Mikrochim. Acta 1996,122, 27–33.

    Article  CAS  Google Scholar 

  102. Liu, W.P.; Liu, Q.P.Fresenius' J. Anal. Chem. 1994,350, 671–673.

    Article  CAS  Google Scholar 

  103. Liu, Q.P.; Wang, Y.C.; Liu, L.C.; Cheng, J.K.Anal. Sci. 1993,9, 523–528.

    CAS  Google Scholar 

  104. Liu, Q.; Liu J.; Tonk, Y.; Cheng, J.Anal. Chim. Acta 1992,269, 223–228.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Division of Analytical Chemistry, Institute of Environmental Chemistry and Technology, Faculty of Chemistry, University of Technology, 612 00, Brno, Czech Republic

    L. Sommer & R. Vlašánková

Authors
  1. L. Sommer
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. Vlašánková
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sommer, L., Vlašánková, R. A survey of the potential of the high performance liquid chromatography and capillary zone electrophoresis for the determination of platinum and platinum group metals. Chromatographia 52, 692–702 (2000). https://doi.org/10.1007/BF02490992

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02490992

Key Words

Search

Navigation