Skip to main content
SpringerLink
Log in

Role of protons in methyl phenyl sulfide oxidation with hydrogen peroxide catalyzed by Ti(IV)-monosubstituted heteropolytungstates

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

Acid tetrabutylammonium salts of Ti(IV)-monosubstituted heteropolytungstate, PW11TiO40 5−, show high catalytic acitivity in the oxidation of methyl phenyl sulfide with hydrogen peroxide, while the corresponding tetrabutylammonium salts containing no protons are poor catalysts for this reaction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M.T. Pope:Heteropoly and Isopoly Oxometalates, Springer Verlag, New York, 1983.

    Google Scholar 

  2. C.L. Hill, C.M. Prosser-McCartha:Coord. Chem. Rev.,143, 407 (1995).

    Article  CAS  Google Scholar 

  3. O.A. Kholdeeva, R.I. Maksimovskaya, G.M. Maksimov, K.I. Zamaraev:React. Kinet. Catal. Lett.,63, 95 (1998).

    CAS  Google Scholar 

  4. G.M. Maksimov, R.I. Maksimovskaya, I.V. Kozhevnikov:Zh. Neorg. Khim.,37, 2279 (1992).

    CAS  Google Scholar 

  5. G.M. Maksimov, G.N. Kustova, K.I. Matveev, T.P. Lazarenko:Koord. Khim.,15, 788 (1989).

    CAS  Google Scholar 

  6. G.M. Maksimov, L.I. Kuznetsova, K.I. Matveev, R.I. Maksimovskaya:Koord. Khim.,11, 1353 (1985).

    CAS  Google Scholar 

  7. R.G. Finke, B. Rapko, R.J. Saxton, P.J. Domaille:J. Am. Chem. Soc.,108, 2947 (1986).

    Article  CAS  Google Scholar 

  8. O.A. Kholdeeva, G.M. Maksimov, R.I. Maksimovskaya, L.A. Kovaleva, M.A. Fedotov, manuscript in preparation.

  9. S.P. Harmalker, M.T. Pope:J. Inorg. Biochem.,28, 85 (1986).

    Article  CAS  Google Scholar 

  10. O. A. Kholdeeva, R.I. Maksimovskaya:Zh. Neorg. Khim.,37, 1349 (1992).

    CAS  Google Scholar 

  11. H.J. Ledon, F. Varescon:Inorg. Chem.,23, 2735 (1984).

    Article  CAS  Google Scholar 

  12. M.G. Clerici:Appl. Catal.,68, 249 (1991).

    Article  CAS  Google Scholar 

  13. M.G. Clerici, P. Ingallina:J. Catal.,140, 71 (1993).

    Article  CAS  Google Scholar 

  14. F. Maspero, U. Romano:J. Catal.,146, 476 (1994).

    Article  CAS  Google Scholar 

  15. G. Bellussi, A. Cazati, M.G. Clerici, G. Maddinelli, R. Millini:J. Catal.,133, 220 (1992).

    Article  CAS  Google Scholar 

  16. E. P. Talsi, D. E. Babushkin:J. Mol. Catal. A: Chemical,106, 179 (1996).

    Article  CAS  Google Scholar 

  17. O. Bortolini, C. Campello, F. Di Furia, G. Modena:J. Mol. Catal.,14, 63 (1982).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis, 630090, Novosibirsk, Russia

    O. A. Kholdeeva, G. M. Maksimov, R. I. Maksimovskaya, L. A. Kovaleva & M. A. Fedotov

Authors
  1. O. A. Kholdeeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. M. Maksimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. I. Maksimovskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. A. Kovaleva
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. A. Fedotov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kholdeeva, O.A., Maksimov, G.M., Maksimovskaya, R.I. et al. Role of protons in methyl phenyl sulfide oxidation with hydrogen peroxide catalyzed by Ti(IV)-monosubstituted heteropolytungstates. React Kinet Catal Lett 66, 311–317 (1999). https://doi.org/10.1007/BF02475806

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02475806

Keywords

Search

Navigation