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Effect of vitrification method on the formation of deep traps for gas molecules inn-butanol glass

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Abstract

The capture of oxygen molecules by deep traps during oxygen diffusion in butanol glasses has been studied at 77 K as the kinetics of thetert-butyl radical oxidation. Slow glass formation in the samples increases the concentration of deep traps in the matrix. The total value of nonrelaxed free volume has no effect on the concentration of deep traps. It is assumed that trap formation is due to the formation of certain molecular structures below room temperature, most probably, with dissolved gas molecules.

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References

  1. H.L. Frisch, S.A. Stern:Crit. Rev. Solid State Mater. Sci.,11, 123 (1983).

    CAS  Google Scholar 

  2. T.M. Aminabhavi, U.S. Aithal, S.S. Shukla:J. Macromol. Sci. C,28, 421 (1988).

    Google Scholar 

  3. W.R. Vieth:Membrane Systems: Analysis and Design, Haser Publishers, New York 1988.

    Google Scholar 

  4. S.V. Vasenkov, S.V. Tolkatchev:J. Chem. Biochem. Kinet.,1, 357 (1991).

    CAS  Google Scholar 

  5. S.V. Vasenkov, S.V. Tolkatchev:Kinet. Katal,33, 1064 (1992).

    CAS  Google Scholar 

  6. S.V. Vasenkov, V.A. Tolkatchev, N.M. Bazhin:Chem. Phys. Lett.,207, 51 (1993).

    Article  CAS  Google Scholar 

  7. S.V. Vasenkov, V.V. Korolev, V.A. Tolkatchev:Chem. Phys.,195, 305 (1995).

    Article  CAS  Google Scholar 

  8. V.M. Zaskulnikov, V.L. Vyazovkin, B.V. Bolshakov, V.A. Tolkatchev:Int. J. Chem. Kinet.,13, 707 (1981).

    Article  CAS  Google Scholar 

  9. V.B. Kogan, V.M. Fridman, V.V. Kafarov:Solubility Handbook,1, Book 1, p. 564, 572, AN SSSR, Moscow, Leningrad 1962 (in Russian).

    Google Scholar 

  10. S.V. Vasenkov, V.A. Tolkatchev:React. Kinet. Catal. Lett.,64, 325 (1998).

    CAS  Google Scholar 

  11. S.V. Vasenkov, V.A. Tolkatchev:Kinet. Katal.,33, 448 (1992).

    CAS  Google Scholar 

  12. K. Toi, D.R. Paul:Macromolecules,15, 1104 (1982).

    Article  CAS  Google Scholar 

  13. K. Toi, G. Morel, D.R. Paul:J. Appl. Polym. Sci.,27, 2997 (1982).

    Article  CAS  Google Scholar 

  14. S.V. Vasenkov, V.A. Tolkatchev:Khim. Fiz.,14, 105 (1995).

    CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Chemical Kinetics and Combustion, 630090, Novosibirsk, Russia

    B. V. Bolshakov & V. A. Tolkatchev

  2. Novosibirsk State University, 630090, Novosibirsk, Russia

    E. A. Korobkova

Authors
  1. B. V. Bolshakov
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  2. E. A. Korobkova
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  3. V. A. Tolkatchev
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Bolshakov, B.V., Korobkova, E.A. & Tolkatchev, V.A. Effect of vitrification method on the formation of deep traps for gas molecules inn-butanol glass. React Kinet Catal Lett 68, 325–330 (1999). https://doi.org/10.1007/BF02475520

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  • DOI: https://doi.org/10.1007/BF02475520

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