Abstract
In contrast to Pd/SiO2, Pd/diamond is extremely dispersed in the H2 atmosphere up to 400°C. Turnover number of Pd/diamond in benzene hydrogenation remains almost constant in a wide range of Pd particle size (15–100 Å) and is 5 times lower than that of Pd/SiO2.
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Kirillov, V.L., Zaikovskii, V.I. & Ryndin, Y.A. Stability and activity of Pd nanoparticles on silica and ultradispersed diamond. React Kinet Catal Lett 64, 169–175 (1998). https://doi.org/10.1007/BF02475385
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DOI: https://doi.org/10.1007/BF02475385