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Retention system, thermodynamic properties and structure correlations of environmental analytes

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Summary

A composite chromatographic retention index system has been developed for identifying polycyclic aromatic hydrocarbons, polychlorinated biphenyls and polychlorinated pesticides. When retention indices and thermodynamic data of polycyclic aromatic hydrocarbons on 5% phenylmethylsiloxane stationary phase were compared with those obtained on polydimethylsiloxane a correlation was found between retention and electronic properties. Determination and quantitation of individual contaminants in water and sediment samples from Lake Mecoacán were achieved by capillary gas chromatography with flame ionization and electrocapture detection.

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Author notes

  1. G. Armeta-Arteaga

    Present address: Universidad Juárez Autónoma de Tabasco, D. A. Ciencias Biológicas, Km. 0.5 Villahermosa-Cárdenas, Villahermosa, 86090, Tabasco, México

Authors and Affiliations

  1. Centro de Química, Instituto de Ciencias, Universidad Autónoma de Puebla, Pue.72571, Apdo. Postal J-55, Puebla, México

    G. Armeta-Arteaga & M. P. Elizalde-González

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  1. G. Armeta-Arteaga
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  2. M. P. Elizalde-González
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Armeta-Arteaga, G., Elizalde-González, M.P. Retention system, thermodynamic properties and structure correlations of environmental analytes. Chromatographia 49, 385–390 (1999). https://doi.org/10.1007/BF02467611

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  • DOI: https://doi.org/10.1007/BF02467611

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