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On-line extraction and determination of carbofuran in raw milk by direct HPLC injection on an ISRP column

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Summary

A method has been developed for extraction and determination of carbofuran in milk. The method involved direct injection of raw milk on to a human serum albumin dimethyloctyl-silica gel (HSA-C8) column and the use of 80:20 (v/v) 0.01 M phosphate buffer pH 5.5-acetonitrile as mobile phase. UV spectrophotometric detection was performed at 220 nm. Identification was based on retention time. Quantification was performed by automatic peak-area determination and was calibrated by use of an external standard.

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Authors and Affiliations

  1. Faculdade de Ciencias, Departmento de Quimica, Universidade Estadual Paulista-UNESP, Av. Edmundo C. Coube S/N, Bauru, CEP-17033-360, Sao Paulo, Brasil

    M. L. Menezes

  2. Laboratoire de Chimie Organique et Organomtétallique (ENSCPB/CNRS-URA), Av. Pey Berland (PB-108), 33402, Talence, France

    G. Felix

  3. Laboratorio de Bioquimica, Universidade do Sagrado Coracão-USC, Rua Irma Arminda, 10-50, Bauru, CEP-17044-160, São Paulo, Brasil

    A. C. C. O. Demarchi

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  1. M. L. Menezes
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  2. G. Felix
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  3. A. C. C. O. Demarchi
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Menezes, M.L., Felix, G. & Demarchi, A.C.C.O. On-line extraction and determination of carbofuran in raw milk by direct HPLC injection on an ISRP column. Chromatographia 47, 81–83 (1998). https://doi.org/10.1007/BF02466790

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  • DOI: https://doi.org/10.1007/BF02466790

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