Abstract
Olivine phosphates of general formula LiMPO4 (M=Fe, Co, Ni) were prepared and characterised in order to evaluate new potential cathode materials for secondary lithium ion batteries. The synthesis was performed by soft chemistry methods to avoid problematical and energetic expensive solid state reactions. In all the compounds no secondary phase was detected and the powder morphology was found to be suitable for cathode layers preparation. Only LiFePO4 and LiCoPO4 showed reversible lithium deintercalation-intercalation at 3.5 and 4.8 V vs. Li+/Li, respectively. The LiCoPO4 high potential makes this compound very attractive for high energy batteries, but unfortunately its lifetime appears to be too poor.
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A.K. Padhi, K.S. Nanjundaswamy, J.B. Goodenough, J. Electrochem. Soc.144, 1188 (1997).
A. Yamada, S.-C. Chung, K. Hinokuma, J. Electrochem. Soc.148, A224 (2001).
A.S. Andersson, J.O. Thomas, B. Kalska, L. Haggstrom, Electrochem. Solid State Lett.3, 66 (2000).
O. Garcia Moreno, M. Alvarez Vega, F. Graci-Alvarado, J. Garcia Jaca, J.M. Gallardo Amores, M.L. Sanjuan, U. Amador, Chem. Mater.13, 1570 (2001).
S. Okada, S. Sawa, M. Egashira, J.-I. Yamaki, M. Tabuchi, H. Kageyama, T. Konishi, A. Yoshino, J. Power Sources97–98, 430 (2001).
D.D. MacNeil, Z. Lu, Z. Chen, J.R. Dahn, J. Power Sources108, 8 (2002).
M. Takahashi, S. Tobishima, K. Takei, Y. Sakurai, Solid State Ionics148, 283 (2002).
A. Yamada, M. Hosoya, S.-C. Chung, Y. Kudo, K. Hinokuma, K.-Y. Liu, Y. Nishi, J. Power Sources119–121, 232 (2003).
G. Arnold, J. Garche, R. Hemmer, S. Strböle, C. Voglar M. Wohlfahrt-Meherens, Journal of Power Sources119–121, 247 (2003).
K.S. Prak, J.T. Son, H.T. Chung, S.F. Kim, C.H. Lee, H.G. Kim, Electrochem. Comm.5, 839 (2003).
J. Barker, M.Y. Saidi, J.L. Swoyer, Electrochem. Solid-State Lett.6(3), A53.
H.S. Kim, B.W. Cho, W.I. Cho, Journal of Power Sources132, 235 (2004).
F. Croce, G.B. Appetecchi, A. Deptula, W. Lada, A Ciancia, L. Giorgi, A. Di Bartolomeo, A. Brignocchi, in: New Materials for Fuel Cells and Modern Batteries, Procedings of the Second International Symposium, University of Montreal (1997).
A. Yamada, M. Hosoya, S.C. Chiung, K. Hinokuma, Y. Kudo, K.Y. Liu, in: Materials for Electrochemical Energy Conversion and Storage (A. Manthiram, P.N. Kumta, S.K. Sundaran, G. Ceder, Eds.), American Ceramic Society, Westerville, 2002, p. 189.
B.H. Hamling, Patens US3736160 (1979).
A.S. Andersson, J.O. Thomas, Journal of Power Sources97–98, 498 (2001).
P. Deniard, A.M. Dulac, X. Rocquefelte, V. Grigorova, O. Lebacq, A. Pasturel, S. Jobic, J. Phis. Chem. Solids65, 229 (2004).
J. Wolfenstine, B. Poese, J.L. Allen, Journal of Power Sources138, 281 (2004).
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Ruffo, R., Huggins, R.A., Mari, C.M. et al. Phosphate materials for cathodes in lithium ion secondary batteries. Ionics 11, 213–219 (2005). https://doi.org/10.1007/BF02430379
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DOI: https://doi.org/10.1007/BF02430379