Abstract
Conversion Electron Mössbauer Spectroscopy (CEMS) studies are reported for as-cut and laser melted surfaces of single phase crystalline Fe2Y, Fe23Y6, Fe2Zr, Fe2B and FeB ingots. Disorder and the appearance of a new phase with a low value of the room temperature hyperfine field was observed for the Fe−Y and Fe2Zr ingots even on the as-cut surfaces due to the mechanical processing. In case of these ingots surface melting by ns laser pulses resulted in the formation of amorphous alloys. In case of the Fe−B ingots the formation of amorphous phase by laser melting was observed for Fe2B only, while in case of FeB the low temperature α-FeB modification appeared both, for mechanical processing and laser melting.
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References
K.H.J. Buschow, J. Less-Common Met. 79 (1981) 243.
P.C.M. Gubbens, J.H.F. van Apeldoorn, A.M. van der Kraan and K.H.J. Buschow, J. Phys. F: Metal Phys. 4 (1974) 921.
G.K. Wertheim, V. Jaccarino and J.H. Wernick, Phys. Rev. 135A (1964) 151.
L. Takács, M.C. Cadeville and I. Vincze, J. Phys. F: Metal Phys. 5 (1975) 800.
J. Chappert, J.M.D. Coey, A. Liénard and J.P. Rebouillat, J. Phys. F.: Metal Phys. 11 (1981) 2727.
P.M.L.O. Scholte, M. Tegze, F. van der Woude, K.H.J. Buschow and I. Vincze,Proc. Fifth Int. Conf. on Rapidly Quenched metals, eds. S. Steeb and H. Warlimont (Elsevier Science Publishers B.V., 1985), p. 541.
K.M. Unruh and C.L. Chien, Phys. Rev. B30 (1984) 4968.
T. Nakajima, I. Nagami and H. Ino, Mat. Science Letters 5 (1986) 60.
W. Hoving, F. van der Woude, K.H.J. Buschow and I. Vincze, J. Non-Cryst. Solids 61–62 (1984) 412.
W.B. Pearson,Handbook of Lattice Spacings and Structure of Metals, Vol. 2 (Pergamon, Oxford).
T. Kanaizuka, Phys. Stat. Sol. (a) 69 (1982) 739.
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Fetzer, C., Gránásy, L., Kemény, T. et al. CEMS investigation of near surface structure. Hyperfine Interact 57, 1823–1827 (1990). https://doi.org/10.1007/BF02405728
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DOI: https://doi.org/10.1007/BF02405728