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Determination of the theoretical rate constants for the reduction reactions of lanthanide ions by hydrated electrons

  • Analytical and Separations Chemistry of Actinides
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Abstract

The mechanism of the reduction reaction of lanthanide(III) ions by hydrated electrons in polar solvents has been investigated. The theoretical rate constants for the reaction of hydrated electrons with a number of lanthanide ions have been calculated using the energy gap laws of the charge shift reaction(D+−A→D−A+) and compared with experimental values. With these results, we have explained the large difference of the reaction rates of lanthanide ions with hydrated electrons, which depend upon the kind of lanthanide ion. The calculated results agree almost quantitatively with the experimental values.

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References

  1. J. K. Tomas, S. Gorden, E. J. Hart, J. Phys. Chem., 68 (1964) 1524.

    Google Scholar 

  2. J. H. Baxendale, E. M. Fielden, J. P. Keene, Proc. Roy. Soc., London, (1965) 320.

  3. S. Gorden, in: Pulse Radiolysis,M. Ebert, J. P. Koene, A. J. Swallow, J. H. Baxendale (Eds), Academic Press, London, 1965, p. 285.

    Google Scholar 

  4. M. Fraggi, Y. Tendler, J. Chem. Phys., 56 (1972) 3287.

    Google Scholar 

  5. S. Gorden, J. C. Sullivan, W. A. Mulac et al., Pulse radiolysis of the lanthanide and actinide elements, in: Proc. IV. Tihany Symp. on Radiat. Chem. Budapest, Akad. Kiadó, 1977, p. 753.

    Google Scholar 

  6. T. Kakitani, N. Mataga, J. Phys. Chem. 90 (1986) 993.

    Article  CAS  Google Scholar 

  7. R. A. Marcus, J. Chem. Phys., 24 (1956) 996.

    Google Scholar 

  8. R. A. Marcus, Ann. Rev. Phys. Chem., 15 (1964) 155.

    Article  CAS  Google Scholar 

  9. R. R. Dogonadze, Dokl. Chem. (Engl. Transl.), 124 (1959) 9.

    Google Scholar 

  10. V. G. Levich, R. R. Dogonadze, Collect. Czech. Chem. Comm., 26 (1961) 193.

    CAS  Google Scholar 

  11. V. G. Levich, Adv. Electrochem. Eng., 4 (1966) 249.

    CAS  Google Scholar 

  12. N. R. Kestner, J. Logan, J. Jortner, J. Phys. Chem., 13 (1974) 161.

    Google Scholar 

  13. J. Strup, J. Jortner, J. Chem. Phys., 63 (1975) 4358.

    Google Scholar 

  14. J. J. Ulstrup, Charge Transfer Processes in Condensed Media, Springer-Verlag, Berlin, 1979;D. Devault, Quantum-Mechanical Tunneling in Biological Systems, Cambridge Univ. Press, Cambridge, 2nd ed., 1984;M. D. Newton, N. Sutin, Ann. Rev. Phys. Chem., 35 (1984) 437.

    Google Scholar 

  15. R. A. Marcus, N. Sutin, Biochim. Biophys. Acta, 811 (1985) 265;M. A. Fox, Adv. Photochem., 13 (1986) 237.;K. V. Mikkelsen, M. A. Ratner, Chem. Rev., 87 (1987) 113.

    CAS  Google Scholar 

  16. S. S. Isied, Progr. Inorg. Chem., 32 (1984) 443.

    CAS  Google Scholar 

  17. T. Holstein, Ann. Phys., 8 (1959) 325.

    CAS  Google Scholar 

  18. J. Jortner, J. Chem. Phys., 30 (1959) 839.

    CAS  Google Scholar 

  19. L. Landau, Z. d. Sowjetunion, 3 (1933) 664.

    CAS  Google Scholar 

  20. L. J. Nugent, R. D. Baybarz, J. L. Burnett et al., J. Phys. Chem., 77 (1973) 152.

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Kyungpook National University, 702-701, Taegu, Korea

    Kwang-Pill Lee & Keung-Shik Park

  2. Material & Corrosion Research Laboratory, Korea Electric Power Research Institute, 305-380, Taejon, Korea

    Duck-Won Kang

  3. Science University of Tokyo, Kagurazaka, 162, Tokyo, Japan

    Yasuhiro Yamada

  4. Tokai University, Institute R&D, Shibuya-ku, 151, Tomigaya, Japan

    Shin-ichi Ohno

Authors
  1. Kwang-Pill Lee
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  2. Keung-Shik Park
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  3. Duck-Won Kang
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  4. Yasuhiro Yamada
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  5. Shin-ichi Ohno
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Lee, KP., Park, KS., Kang, DW. et al. Determination of the theoretical rate constants for the reduction reactions of lanthanide ions by hydrated electrons. J Radioanal Nucl Chem 235, 17–20 (1998). https://doi.org/10.1007/BF02385930

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  • DOI: https://doi.org/10.1007/BF02385930

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