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Very high pressure Mössbauer Spectroscopy using Diamond Anvil Cells

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Abstract

The technique of generating very high pressure by means of Diamond Anvil Cells (DAC) for Mössbauer Effect applications is outlined. A comprehensive description is presented of the principles of DAC, modification for the use in Mössbauer Spectroscopy (MS), the Merrill—Bassett and Bassett cells, of pressure measurements, of gasketing and collimation, and of hydrostatic media. Examples of151Eu,119Sn and129I are given, showing the feasibility of DAC applications in MS. Other isotopes with potential use for high pressure MS using DAC are suggested.

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References

  1. H.G. Drickamer, in:Solid-State Physics, ed. F. Seitz and D. Turnbull, Vol. 17 (Academic Press, New York, 1965) p. 1.

    Google Scholar 

  2. H.G. Drickamer, in:Solid-State Physics, ed. F. Seitz and D. Turnbull, Vol. 19 (Academic Press, New York) (1966) p. 135.

    Google Scholar 

  3. H. Frauenfelder and R. Ingalls, in:Applications of the Mössbauer Effect in Chemistry and Solid State Physics (Technical Reports Series, IAEA, Vienna, 1966) No. 50.

    Google Scholar 

  4. H.G. Drickamer, R. Ingalls and C.J. Cotton, The Mössbauer effect at high pressures, in:Physics of Solids at High Pressures, ed. C.T. Tomizuka and R.M. Emerick (Academic Press, New York, 1965).

    Google Scholar 

  5. H.G. Drickamer, S.C. Fung and C.K. Lewis, Jr., High pressure Mössbauer studies, in:Advances in High Pressure Research, ed. R.S. Bradley, Vol. 3 (Academic Press, New York, 1969).

    Google Scholar 

  6. W.B. Holzapfel, High Temperatures-High Pressures 2(1978)241.

    Google Scholar 

  7. D.L. Williamson, in:Mössbauer Isomer Shifts, ed. G.K. Shenoy and F.E. Wagner (North-Holland, Amsterdam, 1978) p. 317.

    Google Scholar 

  8. Pressure is expressed in kbar (kilobar)=103 bar and Mbar (megabar)=106 bar. The unit currently used (MKS) is GPa (gigapascal)=104 bar. 1 bar=105 N m−2=0.9869 atm=1.0197 kg cm−2.

  9. F.E. Huggins, H.K. Mao and D. Virgo, in:Carnegie Institute of Washington Year Book 74(1975)405.

    Google Scholar 

  10. G. Cort, R.D. Taylor and J.O. Willis, J. Appl. Phys. 53(1982)2064.

    Article  ADS  Google Scholar 

  11. R.D. Taylor, G. Cort and J.O. Willis,ibid. 8199.

    ADS  Google Scholar 

  12. Y. Syono, A. Ito, S. Moromoto, T. Suzuki, T. Yagi and S. Akimoto, Solid State Commun. 50(1984)97.

    Article  Google Scholar 

  13. S. Nasu, K. Kurimoto, S. Nagatomo, S. Endo and F.E. Fujita, Hyp. Int. 29(1986)1583.

    Google Scholar 

  14. L. Chow, P.A. Deane, J.M. Farrell, P.A. Magill and L.D. Roberts, Phys. Rev. B33(1986) 3039.

    ADS  Google Scholar 

  15. M. Pasternak, J.N. Farrell and R.D. Taylor, Hyp. Int. 28(1986)837.

    Article  Google Scholar 

  16. J.N. Farrell and R.D. Taylor, Phys. Rev. Lett. 58(1987)2478.

    Article  ADS  Google Scholar 

  17. M. Pasternak and R.D. Taylor, Phys. Rev. B37(1988)8130.

    ADS  Google Scholar 

  18. L. Merrill and W.A. Bassett, Rev. Sci. Instrum. 45(1974)290.

    Article  Google Scholar 

  19. W.A. Bassett, T. Takahasi and P.W. Stock, Rev. Sci. Instrum. 38(1967)37.

    Article  Google Scholar 

  20. A. Jayaraman, Rev. Mod. Phys. 55(1983)65.

    Article  ADS  Google Scholar 

  21. Diamond anvils are currently manufactured by D. Drucker, Amsterdam, and Ramot, Tel Aviv.

  22. H.K. Mao and P.M. Bell, Science 200(1978)1145.

    ADS  Google Scholar 

  23. Variations of the scheme shown in fig. 2 are used at many high pressure laboratories (see P.M. Bell and H.K. Mao, in:Carnegie Institution of Washington Year Book 74(1975)399). The version shown is being used at Tel Aviv University.

    Google Scholar 

  24. G.J.S. Piermarini, S. Block and J.S. Barnett, J. Appl. Phys. 44(1973)5377.

    Article  Google Scholar 

  25. M. Pasternak, J.N. Farrell and R.D. Taylor, Phys. Rev. Lett. 58(1987)575.

    Article  ADS  Google Scholar 

  26. M. Pasternak, M. Van der Heyden and G. Langouche, Nucl. Instrum. Methods, Phys. Res. Sect. B4(1984)152.

    ADS  Google Scholar 

  27. Special 0.09–0.10 carat anvils for57Fe MS, with increased table size and a total thickness of the anvil pair of 2.4 mm, are currently produced by Ramot, P.O. Box 39296, Tel Aviv 61392, Israel.

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Pasternak, M., Taylor, R.D. Very high pressure Mössbauer Spectroscopy using Diamond Anvil Cells. Hyperfine Interact 47, 415–428 (1989). https://doi.org/10.1007/BF02351621

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