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Effects of side-chains ofN-acetylamino acids on the structures of their triphenyltin(IV) complexes

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Abstract

Triphenyltin(IV) complexes ofN-acetylglycine,N-acetyl-L-leucine,N-acetyl-L-asparagine andN-acetyl-L-tyrosine were prepared by two methods and characterized by means of different spectroscopic methods (FTIR, multinuclear,1H,13C and119Sn NMR and119Sn Mössbauer). The spectroscopic data indicated that theN-acetylglycine complex adopts a trigonal-bipyramidal structure in which the monodentate carboxylate and the amide-C=O group are bound to the same organotin(IV) moiety. The other three complexes are linear oligomers in which the planar Ph3Sn(IV) is coordinated axially by a monodentate carboxylate and an amide-C=O from two different ligands. At theC-terminal end of the oligomer chain there is a tetracoordinated tin(IV) with a monodentate carboxylate as donor group.

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Authors and Affiliations

  1. Research Group on Biocoordination Chemistry of the Hungarian Academy of Sciences, A. József University, P.O. Box 440, H-6701, Szeged, Hungary

    N. Buzás, H. Jankovics & K. Burger

  2. Department of Inorganic and Analytical Chemistry, A. József University, Szeged, Hungary

    L. Nagy

  3. Department of Inorganic Chemistry, Westfälische Wilhelms Universität, Münster, Germany

    R. Krämer

  4. Department of Nuclear Chemistry, L. Eötvös University, Budapest, Hungary

    E. Kuzmann & A. Vértes

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  1. N. Buzás
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  2. L. Nagy
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  7. K. Burger
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Buzás, N., Nagy, L., Jankovics, H. et al. Effects of side-chains ofN-acetylamino acids on the structures of their triphenyltin(IV) complexes. J Radioanal Nucl Chem 241, 313–322 (1999). https://doi.org/10.1007/BF02347467

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  • DOI: https://doi.org/10.1007/BF02347467

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