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Possibilities of ED-XRF with radionuclide sources for analysis of plants

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Abstract

A comparative evaluation of the applicability of different radionuclide sources for the determination of toxic elements in plants by ED-XRF is presented.238Pu or109Cd are suggested as most suitable single excitation sources in ED-XRF for monitoring investigations. More elements are determined with a combination of55F/109Cd(238Pu)/241Am. The results obtained by radionuclide ED-XRF analysis of different plants show that the method permits the reliable determination of Br, Ca, Fe, K, Mn, Rb, Sr and Zn in plant bioindicators. For toxic elements like As, Cd, Cu Cr, Hg, Ni, Se and Pb the detection limits of the method are not low enough.

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References

  1. M. Martin, P. Coughtrey, Biological Monitoring of Heavy Metal Pollution, Applied Science Publishers, London and New York, 1982.

    Google Scholar 

  2. B. Markert, Plants as Biomonitors, VCH, Weinheim, Germany, 1993.

    Google Scholar 

  3. B. Markert, Instrumental Element and Multi-Element Analysis of Plant Samples, John Wiley & Sons, 1996.

  4. D. Tsalev, Electrothermal Atomic Absorption Spectrometry, in: Encyclopedia of Environmental Analysis and Remediation,R. Meyers (Ed.), Vol. 3, John Wiley & Sons, Inc., New York, 1998, p. 1583.

    Google Scholar 

  5. M. Stoeppler, Analytical Chemistry of Metals and Metal Compounds, in: Metals and Their Compounds in the Environment,E. Merian (Ed.), VCH, Weinheim, 1991, p. 106.

    Google Scholar 

  6. R. Severson, L. Cough, G. van den Boom, Water, Air Soil Pollut., 61 (1992) 169.

    Article  CAS  Google Scholar 

  7. R. Djingova, Ju. Ivanova, I. Kuleff, J Radioanal. Nucl. Chem., 237 (1998) 25.

    CAS  Google Scholar 

  8. J. S. Becker, H. J. Dietze, Spectrochim. Acta B, (1998) in press.

  9. R. Djingova, S. Arpadjian, I. Kuleff, Fresenius J. Anal. Chem., 339 (1991) 181.

    Article  Google Scholar 

  10. Z. Alfassi, Activation Analysis, CRC Press, Boca Raton, Florida, 1990, p. 617.

    Google Scholar 

  11. J. Tölgyessy, E. Havranek, E. Dejmkova, Radionuclide X-ray Fluorescence Analysis with Environmental Applications, Elsevier, Amsterdam, 1990.

    Google Scholar 

  12. P. Hahn-Weinheimer, A. Hirner, K. Weber-Diefenbach, Grund und Praktische Anwendung der Röntgenfluorescenz Analyse, Fried Vieweg & Sohn, Braunschweig, Wiesbaden, 1984.

    Google Scholar 

  13. J. J. LaBrecque, Progr. Anal. Atom Spectrosc., 4 (1981) 191.

    CAS  Google Scholar 

  14. J. S. Watt, Intern. J. Appl. Radiation Isotopes, 18 (1967) 363.

    Article  Google Scholar 

  15. D. E. Leyden, Fundamentals of X-ray Spectrometry as Applied to Energy Dispersive Techniques, Tracor X-ray, Inc., Mountain View, California 1984.

    Google Scholar 

  16. R. Jenkis, W. Gould, D. Gedcke, Quantitative X-ray Spectrometry, Marsel Denker, New York, 1981.

    Google Scholar 

  17. L. Currie, Anal. Chem., 323 (1986) 801.

    Google Scholar 

  18. BIMC/IEC/ISO/OIML. International Vocabulary of Basic and General Terms in Metrology, International Organization of Standardization, Geneva, Switzerland, 1984.

    Google Scholar 

  19. ISO, Statistics: Vocabulary and Symbols. Part 1: Probability and General Statistical Terms, Revision of ISO 3534-1977, International Organization of Standardization, Geneva, Switzerland, 1984.

    Google Scholar 

  20. Ju. Ivanova, R. Djingova, I. Kuleff, J. Radioanal. Nucl. Chem., 238 (1998) 29.

    CAS  Google Scholar 

  21. M. Belakova, E. Havranek, A. Bumbalova, J. Radioanal. Nucl. Chem., 201 (1995) 431.

    CAS  Google Scholar 

  22. D. Peev, A. Artinjan, E. Nicolova, S. Tzoneva, N. Valjovska, Phytomonitoring in Rila Mountain—1994. I. Microtopography, Heavy Metals, Statistics and Karyology of the Control Populations, in: Observatoire de Montagne de Moussala-OM2, S, 3, 1995, p. 150.

  23. E. Nicolova, A. Artinjan, Personal communication.

  24. A. Rachetti, W. Wegsheider, Anal. Chim. Acta 188 (1986) 37.

    Article  CAS  Google Scholar 

  25. S. Kumar, S. Singh, D. Mehta, M. Garg, P. Mangal, P. Trehan, X-ray Spectrom., 18 (1989) 207.

    Article  CAS  Google Scholar 

  26. E. Havranek, A. Bumbalova, M. Harangozo, M. Dejmkova, Radioaktivita a ziv. prostredie, 4 (1981) 289.

    Google Scholar 

  27. B. Holynska, J. Jasion, J. Radioanal. Nucl. Chem., 105 (1986) 71.

    CAS  Google Scholar 

  28. J. Tölgyessy, M. Harangozo, P. Dillinger, J. Radioanal. Nucl. Chem., 176 (1993) 451.

    Google Scholar 

  29. A. Bumbalova, E. Havranek, M. Harangozo, Radiochem. Radioanal. Letters, 54 (1982) 367.

    CAS  Google Scholar 

  30. P. Nagy, A. Pazsit, Agrokémia és Talajtan, 28 (1979) 167.

    CAS  Google Scholar 

  31. J. Bacso, M. Kis-Varga, P. Kovacs, G. Kalinka, J. Radioanal. Nucl. Chem., 81 (1984) 59.

    CAS  Google Scholar 

  32. S. Piorek, J. Radioanal. Chem., 58 (1980) 373.

    CAS  Google Scholar 

  33. T. Paradellis, N. Panayotakis, J. Radioanal. Chem., 59 (1980) 221.

    CAS  Google Scholar 

  34. Sz. Török, Z. Szökefalvi-Nagy, J Radioanal.Chem., 78 (1983) 117.

    Google Scholar 

  35. T. Florkowski, B. Holynska, S. Piorek, X-ray Fluorescence Techniques in Analysis of Environmental Pollutants, in: Proc. Symp., on Measurement Detection and Control of Environmental Pollutants, Vienna, 15–19, March 1976, IAEA, Vienna, 1995, p. 3.

    Google Scholar 

  36. R. Djingova, I. Kuleff, Monitoring of Heavy Metal Pollution by Taraxacum Officinale, in: Plants as Biomonitors,B. Markert (Ed.), VCH, Weinheim, Germany, 1993, p. 435.

    Google Scholar 

  37. R. Djingova, D. Wagner, D. Peshev, Sci. Total Environ., 172 (1995) 151.

    CAS  Google Scholar 

  38. B. Markert, U. Herpin, U. Siewers, J. Berlekamp, H. Lieth, Sci. Total Environ., 182 (1996) 159.

    CAS  Google Scholar 

  39. A. Wyttenbach, S. Bajo, L. Tobler, Th. Keller, Plants Soils, 85 (1985) 313.

    CAS  Google Scholar 

  40. M. Harangozo, J. Kralovic, J. Radioanal. Nucl. Chem., 213 (1996) 207.

    CAS  Google Scholar 

  41. Handbook on Nuclear Activation Data, Technical Reports No. 273, IAEA, Vienna, 1987.

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Ivanova, J., Djingova, R. & Kuleff, I. Possibilities of ED-XRF with radionuclide sources for analysis of plants. J Radioanal Nucl Chem 242, 569–575 (1999). https://doi.org/10.1007/BF02345596

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