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Interaction of 1-acetyl-2-phenyl-5-hydroxy-pyrazolidines withβ-substituted esters on the surface of adsorbents

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The interaction of 1-acetyl-2-phenyl-5-hydroxypyrazolidines with esters of carboxylic acids, having an electron-acceptor group in the β-position, proceeds under neutral conditions on the surface of adsorbents without preliminary activation. The diastereomeric composition of the isomers obtained was determined for derivatives of cyanacetic and nitroacetic esters; the derivative of acetoacetic ester shows keto—enol tautomerism in solution. The possibility of activation of the reactions on the surface of the adsorbent with uhf irradiation was shown.

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Authors
  1. L. A. Sviridova
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  2. G. A. Golubeva
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  3. A. V. Mizgunov
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  4. I. V. Dlinnykh
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  5. V. N. Nesterov
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Additional information

M. V. Lomonosov Moscow State University, Moscow 119899. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 509–515, April, 1997.

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Sviridova, L.A., Golubeva, G.A., Mizgunov, A.V. et al. Interaction of 1-acetyl-2-phenyl-5-hydroxy-pyrazolidines withβ-substituted esters on the surface of adsorbents. Chem Heterocycl Compd 33, 435–440 (1997). https://doi.org/10.1007/BF02321388

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  • DOI: https://doi.org/10.1007/BF02321388

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