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Characterization of C18 chemically modified silica-gel and porous glass phases by high resolution solid state NMR spectroscopy and other physico-chemical methods

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Summary

Two types of packing materials, porous glass (PG) and silica gel (SG) have been modified by mono- and difunctional octadecylchlorosilane. The packing surfaces before and after chemical modification have been characterized by CP/MAS NMR, SIMS, porosimetrical, elemental and chromatographic methods. On the basis of the physico-chemical and chromatographic data the PG and SG (of similar porosity) used as supports of chemically bonded phases for RP HPLC, have been compared.

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Buszewski, B. Characterization of C18 chemically modified silica-gel and porous glass phases by high resolution solid state NMR spectroscopy and other physico-chemical methods. Chromatographia 29, 233–242 (1990). https://doi.org/10.1007/BF02317910

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