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Characterization of some commercial poly (styrene-divinylbenzene) copolymers for reversed-phase HPLC1

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Summary

The properties of the poly(styrene-divinylbenzene) copolymers PRP-1 and PLRP-S have been studied by infrared spectroscopy and chromatographic techniques. The following results were obtained:

PRP-1 and PLRP-S are spectroscopically very similar. Their surfaces are chemically neither homogeneous nor stable during use. Retained nonpolar solutes should be eluted with a mobile phase containing tetrahydrofuran. Uncharged acids and anions can be chromatographed without difficulty. Cations of amines should be chromatographed only with a mobile phase of low pH. Uncharged amino-alcohols cannot be chromatographed without the addition of a competitor.

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Author notes

  1. H. W. Stuurman

    Present address: Shimadzu (Europa) GmbH, Ackerstraße 111, D-4000, Düsseldorf, FRG

Authors and Affiliations

  1. Chromatography Department, Max-Planck-Institut für Kohlenforschung, Postfach 10 13 53, D-4330, Mülheim/Ruhr, FRG

    H. W. Stuurman & J. Köhler

  2. Department of Analytical Chemistry, AB Hässle, S-431 83, Mölndal, Sweden

    S. -O Jansson & A. Litzén

Authors
  1. H. W. Stuurman
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  2. J. Köhler
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  3. S. -O Jansson
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  4. A. Litzén
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Stuurman, H.W., Köhler, J., Jansson, S.O. et al. Characterization of some commercial poly (styrene-divinylbenzene) copolymers for reversed-phase HPLC1 . Chromatographia 23, 341–349 (1987). https://doi.org/10.1007/BF02316180

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  • DOI: https://doi.org/10.1007/BF02316180

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