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Comparison of octadecyl-bonded silica and styrene-divinylbenzene copolymer sorbents for trace enrichment purposes fundamental aspects II. Linear chromatographic behaviour of the extracting supports

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Summary

Two reversed-phase LC systems were investigated by frontal analysis for the determination of linear chromatographic conditions, as defined according to the isotherm concept. The Partisil ODS-3 bonded silica and the PRP-1 polystyrene-divinylbenzene resin were used as stationary phases together withtrans-2-hexen-al as test solute and methanol-water mixtures as mobile phases. Particular attention was paid to the respective influence of the two main parameters which may cause sorbent overloading, that is, the capacity factor (k′) and the solute concentration in the mobile phase (Cm). Provided that k′Cm≤10−2 M, linear chromatographic behaviour was observed for both sorbents, the maximum capacities of which were found greater than 1mmolg−1.

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Author notes

  1. S. Bitteur

    Present address: Laboratoire des Arômes et des Substances Naturelles, Institut National de la Recherche Agronomique, Institut des Produits de la Vigne Place Viala, 34060, Montpellier cedex, France

Authors and Affiliations

  1. Laboratoire de Recherches sur les Arômes, Institut National de la Recherche Agronomique, 17 rue Sully, 21000, Dijon, France

    S. Bitteur

  2. Laboratoire de Chimie Analytique, Ecole Supérieure de Physique et de Chimie de Paris, 10 rue Vauquelin, 75005, Paris, France

    R. Rosset

Authors
  1. S. Bitteur
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  2. R. Rosset
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Bitteur, S., Rosset, R. Comparison of octadecyl-bonded silica and styrene-divinylbenzene copolymer sorbents for trace enrichment purposes fundamental aspects II. Linear chromatographic behaviour of the extracting supports. Chromatographia 23, 163–168 (1987). https://doi.org/10.1007/BF02311473

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  • DOI: https://doi.org/10.1007/BF02311473

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