Chemistry of Heterocyclic Compounds

, Volume 33, Issue 5, pp 527–531 | Cite as

1,7-migration of benzyl group in 2-substituted N-benzylindoles

  • Sh. A. Samsoniya
  • I. Sh. Chikvaidze
  • É. O. Gogrichiani
  • N. N. Machaidze
  • Z. E. Saliya
Article

Abstract

It has been shown that when 2-substituted N-benzylindoles are heated above 100°C in polyphosphoric acid, the benzyl group is split off and undergoes 1,7-migration.

Keywords

Organic Chemistry Benzyl Polyphosphoric Acid 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    W. J. Houlihan (ed.), Indoles, Part 1, Wiley, New York (1972), p. 135.Google Scholar
  2. 2.
    Sh. A. Samsoniya, I. Sh. Chikvaidze, and É. O. Gogrichiani, Khim. Geterotsikl. Soedin., No. 8, 1146 (1994).Google Scholar
  3. 3.
    S. Al-Azawe and G. Y. Sarkis, J. Chem. Eng. Data,18, No. 1, 109 (1973).Google Scholar
  4. 4.
    N. N. Suvorov, Yu. I. Smushkevich, V. S. Velezheva, V. S. Rozhkov, and S. V. Simakov, Khim. Geterotsikl. Soedin., No. 2, 191 (1976).Google Scholar
  5. 5.
    R. A. Khmel'nitskii, V. I. Vysotskii, I. I. Grandberg, A. N. Kost, and V. A. Budylin, Zh. Org. Khim.,7, 1514 (1971).Google Scholar

Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • Sh. A. Samsoniya
  • I. Sh. Chikvaidze
  • É. O. Gogrichiani
  • N. N. Machaidze
  • Z. E. Saliya

There are no affiliations available

Personalised recommendations