Skip to main content
SpringerLink
Log in

Chiral separation of polychlorinated biphenyls by micellar electrokinetic chromatography with γ-cyclodextrin as modifier in the separation buffer

  • Originals
  • Published:
Chromatographia Aims and scope Submit manuscript

Summary

Cyclodextrin-modified micellar electrokinetic chromatography has enabled the chiral separation of polychlorinated biphenyls (PCBs). Twelve PCBs (45, 84, 88, 91, 95, 132, 136, 139, 149, 171, 183 and 196) were individually separated into their two enantiomers by using γ-cyclodextrin as modifier in a separation buffer containing 2-(N-cyclohexylamino)ethanesulphonic acid (CHES) and sodium dodecyl sulphate (SDS) micelles. Multicomponent separations were also performed. The separation of the eighteen enantiomers of a mixture of nine chiral PCBs has been performed in a short analysis time (ca. 35 min).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. W. A. König, B. Gehrcke, T. Runge, C. Wolf, J. High Resolut. Chromatogr.16, 376 (1993).

    Google Scholar 

  2. A. Glausch, G. J. Nicholson, M. Fluck, V. Schurig, J. High Resolut. Chromatogr.17, 347 (1994).

    Google Scholar 

  3. P. de Voogt, P. Haplund, L. B. Reutergardh, C. de Wit, F. Waern, Anal. Chem.66, 305A (1994).

    Google Scholar 

  4. S. Fachetti, Mass Spectrometry Rev.12, 173 (1993).

    Google Scholar 

  5. K. L. E. Kaiser, Environ. Pollut.7, 93 (1974).

    Google Scholar 

  6. Dioxin '94. Short Papers. Organohalogen Compounds, Vol.20, Eds. H. Fiedler et al., 15 (1994).

  7. V. Schurig, A. Glausch, Naturwissenschaften80, 468 (1993).

    Google Scholar 

  8. J. H. Hardt, C. Wolf, B. Gehrcke, D. H. Hochmuth, B. Pfaffenberger, H. Hühnerfuss, W. A. König, J. High Resolut. Chromatogr.17, 859 (1994).

    Google Scholar 

  9. S. Terabe, Y. Miyashita, Y. Ishihama, O. Shibata, J. Chromatogr.636, 47 (1993).

    Google Scholar 

  10. S. Terabe, Y. Miyashita, O. Shibata, E. R. Barnhart, L. R. Alexander, D. G. Patterson, B. L. Karger, K. Hosoya, N. Tanaka, J. Chromatogr.516, 23 (1990).

    Google Scholar 

  11. K. Ballschmiter, M. Zell, Fresenius' Z. Anal. Chem.302, 20 (1980).

    Google Scholar 

  12. M. A. García, M. L. Marina, J. C. Díez-Masa, J. Chromatogr. A, in press.

  13. H. J. Isaaq, Instrumentation Sci. & Technol.22, 119 (1994).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Departamento de Química Analítica, Facultad de Ciencias, Universidad de Alcalá de Henares, 28871 Alcalá de Henares, Madrid, Spain

    M. L. Marina & I. Benito

  2. Instituto de Química Orgánica General (C.S.I.C.), Juan de la Cierva 3, 28006, Madrid, Spain

    J. C. Díez-Masa & M. J. González

Authors
  1. M. L. Marina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. Benito
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. C. Díez-Masa
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. J. González
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Marina, M.L., Benito, I., Díez-Masa, J.C. et al. Chiral separation of polychlorinated biphenyls by micellar electrokinetic chromatography with γ-cyclodextrin as modifier in the separation buffer. Chromatographia 42, 269–272 (1996). https://doi.org/10.1007/BF02290308

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02290308

Key Words

Search

Navigation