Homogeneous decomposition of gaseous formic acid induced by a carbon dioxide laser

Abstract

Kinetic parameters of the decomposition of gaseous formic acid induced by laser heating under homogeneous conditions have been determined.

$$\begin{gathered} K = 10^{14.5{\text{ }} \pm {\text{ }}0.9} \exp \left( { - \frac{{66000{\text{ }} \pm {\text{ }}3800}}{{RT}}} \right)\sec ^1 \hfill \\ K = 10^{15.0{\text{ }} \pm {\text{ }}0.9} \exp \left( { - \frac{{66700{\text{ }} \pm {\text{ }}4000}}{{RT}}} \right)\sec ^1 \hfill \\ K = 10^{13.5{\text{ }} \pm {\text{ }}0.8} \exp \left( { - \frac{{61700{\text{ }} \pm {\text{ 36}}00}}{{RT}}} \right)\sec ^1 \hfill \\ \end{gathered} $$

Abstract

С помощью методики лазерного нагрева получены кинетические параметры реакции распада газообразной муравьинойкислоты в гомогенных условиях:

$$\begin{gathered} K = 10^{14.5{\text{ }} \pm {\text{ }}0.9} \exp \left( { - \frac{{66000{\text{ }} \pm {\text{ }}3800}}{{RT}}} \right)ceK^1 \hfill \\ K = 10^{15.0{\text{ }} \pm {\text{ }}0.9} \exp \left( { - \frac{{61700{\text{ }} \pm {\text{ }}4000}}{{RT}}} \right)ceK^1 \hfill \\ K = 10^{13.5{\text{ }} \pm {\text{ }}0.8} \exp \left( { - \frac{{61700{\text{ }} \pm {\text{ 36}}00}}{{RT}}} \right)ceK^1 \hfill \\ \end{gathered} $$