Summary
The retention behaviour of a group of polycyclic aromatic hydrocarbons having nearly equal ionization potentials but different molecular polarizability values was investigated by reversed-phase HPLC and gas chromatography, using β-cyclodextrin as a selective inclusion reagent. In HPLC, the cyclodextrin was applied as an additive to the ethanolwater binary mobile phase, while in gas chromatography β-cyclodextrin served as the stationary phase coated on an inert support. The relationships between the capacity factors, molecular polarizabilities and the shape parameter of solute molecules is discussed.
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Lamparczyk, H., Zarzycki, P., Ochocka, R.J. et al. Retention behavior of the inclusion complexes of some polycyclic aromatic hydrocarbons with β-cyclodextrin. Chromatographia 31, 157–162 (1991). https://doi.org/10.1007/BF02274565
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DOI: https://doi.org/10.1007/BF02274565