Summary
Intermolecular interactions between the solute and the moieties constituting the mobile phase significantly contribute to the overall retention pattern of a given solute in a given chromatographic system. In this paper retention of solute is discussed in the case of the B+AB1+AB2 type mobile phase, which, in a quasithermodynamic way, can be divided into seven individual moieties. One evaluates the influence of each moiety on solute retention, and refers these regularities to the polarity of the solutes.
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Kowalska, T. On the mechanism of solute retention in RP-HPLC systems with B+AB1+AB2 type eluents. Chromatographia 31, 119–122 (1991). https://doi.org/10.1007/BF02274557
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DOI: https://doi.org/10.1007/BF02274557