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Relations entre la composition d'éluants binaires et la retention des solutés en chromatographie d'adsorption sur couche mince

Influence de la phase vapeur et de la démixtion de l'éluant

Relationships between the composition of binary solvents and the solute retention in thin-layer adsorption chromatography

Influence of the vapour phase and eluent demixing

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Summary

The effect of the composition of binary developing solvents of the type: hydrocarbon-ketone on electrondonor solute retention (XYZP (0)) was investigated. Relationships between RM values of substances and the log (mole fraction) of polar component were studied in different development conditions in which the importance of vapour phase and demixing phenomena are variable. According to experimental conditions linear relationships have been established in different concentration ranges of polar solvent.

Résumé

Le présent article traite de l'influence de la composition de solvants binaires de développement (du type hydrocarbure-cétone) sur la rétention de solutés donneurs d'électrons (du type XYZP (0)). Les relations entre le RM du soluté et le logarithme de la fraction molaire en solvant actif dans le mélange éluant ont été étudiées dans différentes conditions de développement permettant de faire varier l'importance de la phase vapeur du solvant et celle des phénomènes de démixtion. Suivant les conditions expérimentales, des relations linéaires ont pu être établies dans différents domaines de concentration de l'éluant en solvant actif.

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Authors and Affiliations

  1. Equipe de Recherche Associée au C.N.R.S. no 474, Laboratoire de Chimie Analytique, Université de Lyon 1, 43 Bd du 11 Novembre 1918, F-69621, Villeurbanne, France

    M. Marichy-Viricel & A. Lamotte

Authors
  1. M. Marichy-Viricel
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  2. A. Lamotte
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Marichy-Viricel, M., Lamotte, A. Relations entre la composition d'éluants binaires et la retention des solutés en chromatographie d'adsorption sur couche mince. Chromatographia 10, 244–249 (1977). https://doi.org/10.1007/BF02274474

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  • DOI: https://doi.org/10.1007/BF02274474

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