Summary
A gas-liquid chromatographic method has been used for direct determination of the partition coefficients (KD) of alcohols, ethers and ketones between olive oil and nitrogen. Olive oil was characterised as a stationary phase for gas chromatography. The differential molar enthalpies of solution were also calculated from retention data. Correlations between log KD for olive oil — nitrogen and molecular connectivity indices, differential molar enthalpies of solution, biological activity and partition coefficients for blood-air were obtained.
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Čabala, R., Svobodová, J., Feltl, L. et al. Direct determination of partition coefficients of volatile liquids between oil and gas by gas chromatography and its use in QSAR analysis. Chromatographia 34, 601–606 (1992). https://doi.org/10.1007/BF02269870
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DOI: https://doi.org/10.1007/BF02269870