Summary
The interaction between some polynuclear aromatic hydrocarbons of environmental concern, and sodium dodecylsulphate and hexadecyltrimethylammonium bromide in the presence of methanol, 2-propanol and n-butanol has been evaluated by high-performance liquid chromatography using micellar mobile phases. Solute-micelle association constants have been determined for the compounds investigated. The results show that the addition of the alcohol to the mobile phase decreases the association constant values, methanol <2-propanol <n-butanol, relative to those in the absence of any additive.
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References
W. R. Melander, Cs. Horváth, in “High-Performance Liquid Chromatography: Advances and Perspectives”, Vol. 2, C. S. Horváth, Ed., Academic Press, N. Y., 114 (1980).
M. G. Khaledi, Anal. Chem.60, 876 (1988).
J. G. Dorsey, M. T. DeEchegaray, J. S. Landy, Anal. Chem.55, 924 (1983).
P. Yarmchuk, R. Weinberger, R. F. Hirsh, L. J. Cline-Love, J. Chromatogr.283, 47 (1984).
D. W. Armstrong, J. J. Ward, A. Berthod, Anal. Chem.58, 579 (1986).
M. F. Borgerding, R. L. Williams, W. L. Hinze, F. H. Quina, J. Liq. Chromatogr.12, 1367 (1989).
J. G. Dorsey, Adv. Chromatogr.27, 167 (1987).
F. P. Tomasella, J. Fett, L. J. Cline-Love, Anal. Chem.63, 474 (1991).
M. G. Khaledi, J. K. Strasters, A. H. Rodgers, E. D. Breyer, Anal. Chem.62, 130 (1990).
A. S. Kord, M. G. Khaledi, Anal. Chem.64, 1894 (1992).
M. A. Rodríguez Delgado, M. J. Sánchez, V. González, F. García Montelongo, Fresenius J. Anal. Chem.345, 748 (1993).
V. González, M. A. Rodríguez Delgado, M. J. Sánchez, F. García Montelongo, Chromatographia32, 627 (1992).
M. Arunyanart, L. J. Cline-Love, Anal. Chem.56, 1557 (1984).
E. Bonet Domingo, M. J. Medina Hernández, G. Ramis Ramos, M. C. García Alvarez-Coque, Analyst117, 843 (1992).
M. G. Khaledi, E. Peuler, J. Ngeh-Ngwainbi, Anal. Chem.59, 2738 (1987).
G. L. McIntire, D. M. Chappardi, R. L. Casselberr, H. N. Blount, J. Phys. Chem.86, 2632 (1982).
M. J. Rosen, Surfactants and Interfacial Phenomena, Wiley, New York, 2nd Ed., (1988).
R. J. McGreevy, R. S. Schechter, J. Colloid Interface Sci.127, 209 (1989).
E. Aircart, D. J. Jobe, B. Skalski, R. E. Verrall, J. Phys. Chem.96, 2348 (1992).
J. M. Fendler, E. J. Fendler, Catalysis in Micellar and Macromolecular Systems, Academic Press, New York, (1975).
D. J. Jobe, R. E. Verrall, B. Skalski, E. Aircart, J. Phys. Chem.96, 6811 (1992).
A. Berthod, I. Girard, C. Gonnet, Eds., Ordered Media in Chemical Separations, ACS Symposium Series 342 (1987).
A. Berthod, I. Girard, C. Gonnet, Anal. Chem.58, 1362 (1986).
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Rodríguez Delgado, M.A., Sánchez, M.J., González, V. et al. Solute-micelle association constants of some polynuclear aromatic hydrocarbons by micellar liquid chromatography with alcohol additives to mobile phase. Chromatographia 38, 342–348 (1994). https://doi.org/10.1007/BF02269778
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DOI: https://doi.org/10.1007/BF02269778