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Molecular shape recognition capability of liquid-crystal bonded phases in reversed-phase high performance liquid chromatography

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Summary

The chromatographic retention behaviour of two liquidcrystal bonded phases have been evaluated using polycyclic aromatic hydrocarbons (PAHs) as the probe samples in reversed-phase high performance liquid chromatography (RP-HPLC). The results clearly indicate that these phases have better planarity and shape recognition capabilities than commercially-avaialble polymeric octadecylsilica (ODS) phases whose strong planarity and shape selectivities were found earlier. It can also be concluded from the chromatographic observations that the shape recognition capability of these phases is dependent on both mobile phase composition and column temperature, but that the effect of mobile phase and temperature on the shape selectivity work independently. The retention behaviour can be explained by changes in the phase structure with changes of eluent composition and temperature.

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Author notes

  1. G. Luehr

    Present address: Sandoz Agro, Inc., 94304, Palo Alto, CA, USA

Authors and Affiliations

  1. School of Materials Science, Toyohashi University of Technology, 441, Toyohashi, Japan

    Y. Saito & K. Jinno

  2. Department of Chemistry, San Jose State University, 95192, San Jose, CA, USA

    J. J. Pesek

  3. J & W Scientific, 95630-4714, Folsom, CA, USA

    Y. -L. Chen, G. Luehr & J. Archer

  4. Chevron Research and Technology Company, 94802, Richmond, CA, USA

    J. C. Fetzer & W. R. Biggs

Authors
  1. Y. Saito
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  2. K. Jinno
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  4. Y. -L. Chen
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  5. G. Luehr
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  6. J. Archer
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  7. J. C. Fetzer
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  8. W. R. Biggs
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Saito, Y., Jinno, K., Pesek, J.J. et al. Molecular shape recognition capability of liquid-crystal bonded phases in reversed-phase high performance liquid chromatography. Chromatographia 38, 295–303 (1994). https://doi.org/10.1007/BF02269771

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  • DOI: https://doi.org/10.1007/BF02269771

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