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The determination of thermodynamic parameters of solution by means of the gas-chromatographic retention index. Solution parameters for n-alkanes in different stationary phases

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Summary

The values of KB, ΔFn and ΔHn of n-alkanes for different stationary phases were determined to provide the possibility of the calculation of thermodynamic solution parameters for any substance using its retention index without absolute measurements of retention volumes and without correcting them for experimental conditions.

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Authors and Affiliations

  1. All-Union Research Institute of Synthetic and Natural Odour Substances, Moscow, USSR

    A. S. Leshchiner & S. A. Voitkevich

  2. N. D. Zelinski Institute of Organic Chemistry of the Academy of Sciences of the USSR, Moscow, USSR

    B. A. Rudenko & S. S. Yufit

Authors
  1. A. S. Leshchiner
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  2. S. A. Voitkevich
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  3. B. A. Rudenko
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  4. S. S. Yufit
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Leshchiner, A.S., Voitkevich, S.A., Rudenko, B.A. et al. The determination of thermodynamic parameters of solution by means of the gas-chromatographic retention index. Solution parameters for n-alkanes in different stationary phases. Chromatographia 6, 314–316 (1973). https://doi.org/10.1007/BF02269332

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  • DOI: https://doi.org/10.1007/BF02269332

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