Summary
Sorption of the titanium peroxocomplex on silica gel was studied in dependence on the pH and on the presence of various complexing substances, especially tartaric and citric acids. The distribution coefficients for the titanium peroxocomplex and for some other components were determined. Optimum conditions were established for the separation of small amounts of titanium from a number of accompanying cations and anions on a column and under static conditions.
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References
Yu. A. Zolotov, Zh. Anal. Khim.32, 2805 (1977).
Yu. A. Zolotov, Analyst103, 56 (1978).
Z. Čižek, J. Doležal andZ. Šulcek, Anal. Chim. Acta100, 479 (1978).
J. Pitra andJ. Stěrba, Chem. Listy56, 544 (1962).
L. Ya. Polyak, Zh. Anal. Khim.17, 206 (1962).
D. F. Wood andJ. T. Jones, Anal. Chim. Acta47, 215 (1969).
G. A. Parker andD. F. Boltz, Anal. Lett.1, 679 (1968).
H. M. Ockenden andJ. K. Foreman, Analyst82, 592 (1957).
Analytical Methods for Atomic Absorption Spectrophotometry, Perkin Elmer, Norwalk 1973.
Z. Čižek, Z. Šulcek andJ. Doležal, to be published.
K. J. Buchanan, A. Goosen andJ. D. Lovelock, J. South Afr. Chem. Inst.29, 85 (1976);30, 191 (1977).
C. Walling andM. Clary, Int. J. Chem. Kinet.9, 595 (1977).
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Čížek, Z., Šulcek, Z. & Doležal, J. Sorption of the peroxocomplex of titanium on silica gel and its analytical use. Chromatographia 15, 18–24 (1982). https://doi.org/10.1007/BF02269034
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DOI: https://doi.org/10.1007/BF02269034