Summary
On-column adduct formation has been used to enhance the stability of metal xanthate complexes. useful metal xanthate separations have been achieved by including 1,10 phenanthroline in the chromatographic eluent along with the primary complexing agent.
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Wallace, G.G., Heneghan, G. Separation of metal ions using in-situ complexation chromatography with ethyl xanthate and 1,10 phenanthroline as ligands. Chromatographia 22, 275–277 (1986). https://doi.org/10.1007/BF02268773
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DOI: https://doi.org/10.1007/BF02268773