Summary
The retention of positively and negatively charged and neutral solutes was studied in an aqueous phosphate buffer eluent, with constant inorganic-counterion concentration, on ODS-Hypersil stationary phase in the presence of various sulfonic acid ion-pairing reagents. The adsorption isotherms of the ion-pairing reagents d-camphor-10-sulfonic acid, sodium cyclohexylsulfamic acid and sodium alkylsulfonates (butyl-, hexyl- and octyl-) were determined by the breakthrough method.
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Dedicated to Professor J. F. K. Huber on the occasion of his 60th birthday.
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Bartha, Á., Vigh, G., Billiet, H. et al. Effect of the type of ion-pairing reagent in reversed-phase ion-pair chromatography. Chromatographia 20, 587–590 (1985). https://doi.org/10.1007/BF02263216
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DOI: https://doi.org/10.1007/BF02263216