Skip to main content
SpringerLink
Log in

Studies on some iron complexes using Mössbauer spectroscopy

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Mössbauer spectroscopic studies were carried out on some synthesized iron complexes of Schiff's bases. The studies have evidenced that iron/II/ and iron/III/ species were formed, and no stereoisomers were found. However, the complex of bis/acetylacetone diethylene triamine/ had shown the geometric isomers, and only the Fe/III/ species formed. Immersion of the chelate of iron bis/salicylaldehyde ethylene diamine/ in aerated distilled water for a day had resulted in the conversion of the entire iron/II/ species into the iron/III/ complexes. The exposure to atmosphere had converted a part of iron/II/ into iron/III/ and resulted in distortion of the iron/II/ chelates. This leaves a room to think that oxygen transport or absorption may bring change in the oxidation number of the central metal ion or distortion in the structural arrangements.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R.D. Jones, D.A. Summerville, F. Basolo,Chem. Rev., /Am. Chem. Soc./, 79 /1979/ 139.

    Google Scholar 

  2. P. Pfeiffer, E. Breith, E. Lubbe, T. Tsumaki,Ann. Chem. Liebigs, 503 /1933/ 84.

    Google Scholar 

  3. T. Tsumaki,Bull. Chem. Soc. Japan, 13 /1938/ 252.

    Google Scholar 

  4. M. Calvin, R.H. Bailes, W.K. Wilmarth,J. Am. Chem. Soc., 68 /1946/ 2254.

    Google Scholar 

  5. M. Calvin, C.H. Barkelew,J. Am. Chem. Soc., 68 /1946/ 2267.

    Google Scholar 

  6. H. Diefil, C.C. Hach, G.C. Harrison, L.M. Liggett, T.S. Chen,Iowa State Coll. J. Sc., 21 /1947/ 232.

    Google Scholar 

  7. R.F. Stewart, P.A. Estep, J.J.S. Sebastian, U.S. Bureau Mines Inform. Cir. No. 7906, 1959.

  8. P. Gutlich, in Mössbauer Spectroscopy, Ed. U. Gonser, Springer-Verlag, 1975.

  9. W. Linert, V. Gutmann, G. Baumgartner, G. Weisnhger, H. Kirchmayr,Inorg. Chem. Acta, 74 /1983/ 123.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Physics, University of Jodhpur, Jodhpur, India

    K. Dhoot, R. P. Tripathi & M. L. Jangid

  2. Raksha Prayogshala, 432 001, Jodhpur, India

    M. P. Chacharkar

Authors
  1. K. Dhoot
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. P. Tripathi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. L. Jangid
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. P. Chacharkar
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dhoot, K., Tripathi, R.P., Jangid, M.L. et al. Studies on some iron complexes using Mössbauer spectroscopy. Journal of Radioanalytical and Nuclear Chemistry Letters 119, 489–497 (1987). https://doi.org/10.1007/BF02261211

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02261211

Keywords

Search

Navigation