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Chromatographic and potentiometric determination of dissociation constants of weakly basic Aroma compounds

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Summary

Reversed-phase liquid chromatography on two stationary phases—octadecylbonded silica Partisil ODS-3 and polystyrene-divinylbenzene resin PRP-1—and potentiometric titration in the water/methanol mobile phase were investigated in order to determine the dissociation constants of three weakly basic aroma compounds, namely trimethyl pyrazine, 2,4-dimethyl thiazole and methyl anthranilate. The data obtained from both methods are quite consistent and compare favourably to values found in the literature.

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References

  1. S. Bitteur, R. Rosset, J. Food Sci.,53, 141 (1988).

    Google Scholar 

  2. S. Bitteur, R. Rosset, J. Chromatogr.,394, 279 (1987).

    Google Scholar 

  3. S. Bitteur, R. Rosset, Chromatographia,23 (1987) 163.

    Google Scholar 

  4. A. C. Cumming, Proc. Roy Soc. (London),A78, 163 (1906).

    Google Scholar 

  5. P. Goursot, I. Wadsö, Acta Chem. Scand.,20, 1314 (1966).

    Google Scholar 

  6. R. Phan-Tan-Luu, J.-M. Surzur, J. Metzger, J.-P. Aune, C. Dupuy, Bull. Soc. Chim. France,9, 3274 (1967).

    Google Scholar 

  7. D. A. Keyworth, J. Org. Chem.,24, 1355 (1959).

    Google Scholar 

  8. A. S.-C. Chia, R. F. Trimble, J. Phys. Chem.65, 863 (1961).

    Google Scholar 

  9. M. D. Grieser, D. J. Pietrzyk, Anal. Chem.,45, 1348 (1973).

    Google Scholar 

  10. C.-H. Chu, D. J. Pietrzyk, Anal. Chem.,46, 330 (1974).

    Google Scholar 

  11. D. J. Pietrzyk, E. P. Kroeff, T. D. Rotsch, Anal. Chem.,50, 497 (1978).

    Google Scholar 

  12. Cs. Horvath, W. Melander, I. Molnar, Anal. Chem.49, 142 (1977).

    Google Scholar 

  13. S. H. Hansen, P. Helboe, U. Lund, J. Chromatogr.,270, 77 (1983).

    Google Scholar 

  14. P. R. Haddad, A. C. J. H. Drouen, H. A. H. Billiet, L. de Galan, J. Chromatogr.,282, 71 (1983).

    Google Scholar 

  15. E. Papp, Gy. Vigh, J. Chromatogr.,282, 59 (1983).

    Google Scholar 

  16. A. Leitold, Gy. Vigh, J. Chromatogr.,257, 384 (1983).

    Google Scholar 

  17. G. Charlot, B. Trémillon, “Les réactions chimiques dans les solvants non aqueux”, Gauthier-Villars, Paris (1963).

    Google Scholar 

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Author notes

  1. S. Bitteur

    Present address: Laboratoire des Arômes et des Substances Naturelles, Institut des Produits de la Vigne, Institut National de la Recherche Agronomique, 9 Place Viala, 34000, Montpellier cedex, France

Authors and Affiliations

  1. Laboratoire de Recherche sur les Arômes, Institut National de la Recherche Agronomique, 17 rue Sully, 21000, Dijon, France

    S. Bitteur

  2. Laboratoire de Chimie Analytique, Ecole Supérieure de Physique et de Chimie de Paris, 10 rue Vauquelin, 75005, Paris, France

    R. Rosset

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  1. S. Bitteur
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  2. R. Rosset
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Bitteur, S., Rosset, R. Chromatographic and potentiometric determination of dissociation constants of weakly basic Aroma compounds. Chromatographia 27, 194–200 (1989). https://doi.org/10.1007/BF02260445

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  • DOI: https://doi.org/10.1007/BF02260445

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