Abstract
The causes of aggregation of particles of oxides prepared by different methods are considered. It is shown that the least aggregated powders are prepared by calcination of poorly soluble compounds precipitated from hot low-concentration solutions. An effective method for deaggregation of the powders of the intermediate compounds is wet crushing. It is recommended that only organic liquids be used in crushing hydroxides.
Similar content being viewed by others
References
I. M. Vasserman,Chemical Precipitation of Solutions [in Russian], Khimiya, Leningrad (1980).
A. P. Kreshkov,Foundations of Analytical Chemistry [in Russian], Vol. 2, Khimiya, Moscow (1976).
A. E. Kozlova, E. S. Lukin, and D. N. Poluboyarinov, “Effect of the calcination temperature and the conditions of preparation of yttrium oxalate on the sintering of yttrium oxide,”Trudy Mosk. Khim.-Tekhnol. Inst. Im. Mendeleeva, Issue82, 54–56 (1974).
A. E. Kozlova, E. S. Lukin, D. N. Poluboyarinov, G. B. Tel'nova, and A. Ya. Petunina, “Effect of the calcination temperature of yttrium oxalate on crushing, pressing, and sintering of Y2O3,”Izv. Akad. Nauk SSSR, Neorg. Mater.,2(10), 1800–1804 (1975).
R. I. Mamedov, E. S. Lukin, T. V. Efimovskaya, and A. E. Kozlova, “Ceramics from yttrium scandate,”Ogneupory, No. 6, 18 – 19 (1983).
I. E. Starik,Foundations of Radiochemistry [in Russian], Khimiya, Moscow (1972).
A. N. Nesmeyanov,Radiochemistry [in Russian], Khimiya, Moscow (1972).
G. B. Tel'nova,Investigation and Development of the Technology of Luminescent Transparent Ceramics Based on Yttrium Oxide Activated by Eu 3+ Ions, Author's Abstract of Candidate's Thesis [in Russian], Moscow (1981).
L. V. Fateeva,A Technology of High-Density Ceramic Materials Based on YAG, Author's Abstract of Candidate's Thesis [in Russian], Moscow (1985).
A. V. Dushina and V. B. Aleskovskii, “Ion exchange as the first stage in the transformation of solid substances in solutions of electrolytes,”Zh. Prikl. Khim.,49(1), 41–49 (1976).
I. I. Nagayuk, E. S. Lukin, T. V. Efimovskaya, and Yu. D. Garazhenko, “Sintering of scandium oxide prepared by decomposition of hydroxides,”Trudy Mosk. Khim.-Tekhnol. Inst. Im. Mendeleeva, Issue116, 29–31 (1981).
V. A. Bron, M. M. Diesperova, L. P. Sudakov, et al., “Activation of sintering processes of magnesium oxide and some engineering products based on it,” in:Chemistry of High-Temperature Materials [in Russian], Nauka, Moscow (1967), pp. 180–185.
E. S. Lukin, L. B. Borovkova, Z. K. Chernikova, and V. V. Bondarev, “Fabrication of shrinkage-free ceramics from magnesium oxide,”Ogneupory, No. 1, 40 – 42 (1974).
E. S. Lukin, L. B. Borovkova, and V. S. Glazachev, “Preparation of transparent ceramics based on yttrium oxide using the method of experimental design,”Steklo Keram., No. 5, 25 – 27 (1977).
Author information
Authors and Affiliations
Additional information
Translated from Ogneupory, No. 2, pp. 9 – 18, February, 1996.
The beginning of the article is in issue No. 1, 1996.
Rights and permissions
About this article
Cite this article
Lukin, E.S. Modern high-density oxide ceramics with controlled microstructure. Part I. Effect of aggregation of oxide powders on the sintering and microstructure of ceramics. Refractories 37, 43–51 (1996). https://doi.org/10.1007/BF02230463
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02230463