Skip to main content
Log in

Speciation of heavy metals in soils based on charge separation

  • Published:
Plant and Soil Aims and scope Submit manuscript

Summary

An experimental approach to the speciation of heavy metals in soil extracts has been developed. The proposed methodology differentiates between differently charged metal species in water and ammonium acetate soil extracts. Furthermore a distinction has been made between labile and stable metal species by using a Chelex 100 chelating ion exchange resin.

Significant differences in heavy metal speciation were found between an untreated soil and the same soil treated with 100 ppm Zn-ions and 100 ppm Zn-EDTA-ions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Abdullah M I and Reusch-Berg B 1981 Metal species in sediments and interstitial water.In Heavy Metals in the Environment. International conference, Amsterdam. pp 669–673.

  2. Badri M A and Aston S R 1981 Fractionation of heavy metals in estuarine sediments.In Heavy Metals in the Environment. International conference, Amsterdam. pp 705–708.

  3. Boust D and Saas A 1981 A selective extraction procedure applied to trace metals; comparison between several reagents and two types of sediments (Seine and Gironde estuaries).In Heavy Metals in the Environment. International conference, Amsterdam. pp 709–712.

  4. Butterworth F E and Alloway B J 1981 Investigations into the speciation of cadmium in polluted soils using liquid chromatography.In Heavy Metals in the Environment. International conference, Amsterdam. pp 713–716.

  5. Cottenie A, Camerlynck R, Verloo M and Dhaese A 1979 Fractionation and determination of trace elements in plants, soils and sediments. Pure Appl. Chem. 52, 45–53.

    Google Scholar 

  6. Cottenie A and Kiekens L 1981 Beweglichkeit von Schwermetallen in mit Schlamm angereicherten Böden. Korrespondenz Abwasser 28, 206–210.

    Google Scholar 

  7. Figura P and McDuffie B 1979 Use of chelex resin for determination of labile trace metal fractions in aqueous ligand media and comparison of the method with anodic stripping voltametry. Anal. Chem. 51, 120–125.

    Google Scholar 

  8. Figura P and McDuffie B 1980 Determination of labilities of soluble trace metal species in aqueous environmental samples by anodic stripping voltametry and chelex column and batch methods. Anal. Chem. 52, 1433–1439.

    Google Scholar 

  9. Förstner U, Calmano W, Conradt K, Jaksch H, Schimkus C and Schoer J 1981 Chemical speciation of heavy metals in solid waste materials (sewage sludge, mining wastes, dredged materials, polluted sediments) by sequential extraction.In Heavy Metals in the Environment. International conference, Amsterdam. pp 697–704.

  10. Garcia-Miragaya J 1981 Levels, chemical forms and solubility of lead in roadside soils of Caracas, Venezuela.In Heavy Metals in the Environment. International conference, Amsterdam. pp 728–732.

  11. Iu K L, Pulford I D and Duncan H J 1981 Influences of waterlogging and lime or organic matter additions on the distribution of trace metals in an acid soil. I. Manganese and iron. Plant and Soil 59, 317–326.

    Google Scholar 

  12. Iu K L, Pulford I D and Duncan H J 1981 Influence of waterlogging and lime or organic matter additions on the distribution of trace metals in an acid soil. II. Zinc and copper. Plant and Soil 59, 327–333.

    Google Scholar 

  13. Kiekens L and Cottenie A 1981 Behaviour of copper in soils.In Copper in Animal Wastes and Sewage Sludge. Ed. D Reidel Publ. Co. pp. 85–101.

  14. Lindsay W L 1979 Chelate equilibria.In Chemical Equilibrium in Soils. pp 239–266. John Wiley and Sons, N.Y.

    Google Scholar 

  15. Mattigod S V 1981 Speciation of heavy metals in soils.In Heavy Metals in the Environment. International conference. Amsterdam. pp 721–727.

  16. Mattigod S V and Sposito G 1979 Chemical modeling of trace metal equilibria in contaminated soil solutions using the computer program GEOCHEM.In Am. Chemical Modeling in Aqueous Systems. ACS symposium series, no 93, Chem. Soc. pp 837–856.

  17. McLaren R G and Crawford D V 1973 Studies on soil copper. I. The fractionation of copper in soils. J. Soil Sci. 24, 172–181.

    Google Scholar 

  18. Németh K 1976 Die effektive und potentielle Nährstoffverfügbarkeit im Boden und ihre Bestimmung mit Elektro-Ultrafiltration (EUF) Habilitationsschrift. Universität Giessen.

  19. Németh K 1979 The availability of nutrients in the soil as determined by Electro-Ultrafiltration (EUF). Adv. Agron. 31, 155–188.

    Google Scholar 

  20. Németh K 1980 Electro-Ultrafiltration with varying Voltage and Temperature during the Extraction Process. Proc. Int. Symp. Application of Electro-Ultrafiltration in the agricultural production, Budapest. pp 17–56.

  21. Sillen L G and Martel E A 1971 Stability Constants of Metal-ion Complexes No 25, The Chemical Society, Burlington House, London.

    Google Scholar 

  22. Sturgeon R E, Berman S S, Desaulniers A and Russell D S 1980 Pre-concentration of trace metals from sea-water for determination by graphite furnace atomic-absorption spectrometry. Talanta 27, 85–94.

    Google Scholar 

  23. Tessier A, Campbell P G C and Bisson M 1979 Sequential extraction procedure for the speciation of particulate trace metals. Anal. Chem. 51, 844–851.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Camerlynck, R., Kiekens, L. Speciation of heavy metals in soils based on charge separation. Plant Soil 68, 331–339 (1982). https://doi.org/10.1007/BF02197938

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02197938

Key words

Navigation