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Determination of the rare-earth elements in phosphate rocks using both inductively coupled plasma atomic emission spectrometry and instrumental neutron activation analysis

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Rare earth elements have been determined in Syrian phosphate rocks by two methods: inductively coupled plasma atomic emission spectrometry following a cation separation, and instrumental neutron activation analysis using both short and long irradiation periods. The results from the two methods agree in most cases apart from Ce, Lu, Nd and Sm. Despite the absence of reliable reference materials, we believe the emission spectrometry technique to be the more accurate.

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References

  1. A.W. Mosen, R.A. Schmitt, J. Vasilevskis,Anal. Chim. Acta, 25 (1961) 10.

    Google Scholar 

  2. F.M. Graber, H.R. Lukens, J.K. Mackenzie,J. Radioanal. Chem., 4 (1970) 229.

    Google Scholar 

  3. A.O. Brunfelt, E. Steinnes,J. Radioanal. Chem., 13 (1973) 11.

    Google Scholar 

  4. A.O. Brunfelt, I. Roelandts, E. Steinnes,J. Radioanal. Chem., 38 (1977) 451.

    Google Scholar 

  5. J. Duffield, G.R. Gilmore,J. Radioanal. Chem., 48 (1979) 135.

    Google Scholar 

  6. E.B. Denechaud, P.A. Helmke, L.A. Haskin,J. Radioanal. Chem., 6 (1970) 97.

    Google Scholar 

  7. R.A. Schmitt, A.W. Mosen, C.S. Suffredini, J.E. Lasch, R.A. Sharp, D.A. Olehy,Nature, 186 (1960) 863.

    Google Scholar 

  8. L.A. Haskin, M.A. Gell,J. Geophys. Res., 67 (1962) 2537.

    Google Scholar 

  9. A. Schofield, L.A. Haskin,Geochim. Cosmochim, Acta, 28 (1964) 437.

    Google Scholar 

  10. J.C. Laul, E.A. Lepel, W.C. Weimer, N.A. Wogman,J. Radioanal. Chem., 69 (1982) 181.

    Google Scholar 

  11. R. Zilliacus, M. Kaistila, R.J. Rosenberg,J. Radioanal. Chem., 71 (1982) 323.

    Google Scholar 

  12. J.L. Joron, G. Ottonello,J. Radioanal. Nucl. Chem., 88 (1985) 259.

    Google Scholar 

  13. Y. Hamajima, M. Koba, K. Endo, H. Nakahara,J. Radioanal. Nucl. Chem., 89 (1985) 315.

    Google Scholar 

  14. G.A. Wandless, J.W. Morgan,J. Radioanal. Nucl. Chem., 92 (1985) 273.

    Google Scholar 

  15. A. Wyttenbach, S. Bajo, L. Tobler,J. Radioanal. Chem., 78 (1983) 283.

    Google Scholar 

  16. J.C. Cobb,Anal. Chem., 39 (1969) 127.

    Google Scholar 

  17. G.E. Gordon, K. Randle, G.G. Goles, J.B. Corliss, M.H. Beeson, S.S. Oxley,Geochim. Cosmochim. Acta, 32 (1968) 369.

    Google Scholar 

  18. J. Rosenberg, H.B. Wilk,Radiochem. Radioanal. Lett., 6 (1971) 45.

    Google Scholar 

  19. A.O. Brunfelt, I. Roelandts,Talanta, 21 (1974), 513.

    Google Scholar 

  20. H. Puchelt, R. Emmermann,Earth Planet. Sci. Lett., 32 (1976) 279.

    Google Scholar 

  21. R.A. Nadkarni,Radiochem. Radioanal. Lett., 25 (1976) 159.

    Google Scholar 

  22. E.I. Zaitsev, D.A. Mineyev, Y.P. Sotskov,J. Radioanal. Chem., 38 (1977) 291.

    Google Scholar 

  23. O.I. Asubiojo, K. Delancey, V.P. Guinn,J. Radioanal. Nucl. Chem., 88 (1985) 389.

    Google Scholar 

  24. J.X. Sun, R.E. Jervis,J. Radioanal. Nucl. Chem., 89 (1985) 553.

    Google Scholar 

  25. P.J. Hooker, R.K. Onions, R.J. Rankhurst,Chem., Geol., 16 (1975) 189.

    Google Scholar 

  26. S.F. Marsh,Anal. Chem., 39 (1967) 641.

    Google Scholar 

  27. M.F. Thirlwall,Chem. Geol., 35 (1982) 155.

    Google Scholar 

  28. C.C. Schnetzler, H.H. Thomas, J.A. Philpotts,Anal. Chem., 39 (1967) 1888.

    Google Scholar 

  29. A. Masuda, N. Nakamura, T. Tanaka,Geochim. Cosmochim. Acta, 37 (1973) 239.

    Google Scholar 

  30. R.K. Onions, K. Grönvold,Earth Planet. Sci. Lett., 19 (1973) 397.

    Google Scholar 

  31. R.W. Kay, P.W. Gast,J. Geol., 81 (1973) 653.

    Google Scholar 

  32. G.D. Nicholls, A.L. Graham, E. Williams, M. Wood,Anal. Chem., 39 (1967) 584.

    Google Scholar 

  33. G.H. Morrison, A.T. Kashuba,Anal. Chem., 41 (1969) 1842.

    Google Scholar 

  34. F.W.E. Strelow, P.F.S. Jackson,Anal. Chem., 46 (1974) 1481.

    Google Scholar 

  35. G.N. Eby,Anal. Chem., 44 (1972) 2137.

    Google Scholar 

  36. I. Roelandts,Anal. Chem., 53 (1981) 676.

    Google Scholar 

  37. P. Robinson, N.C. Higgins, G.A. Jenner,Chem. Geol., 55 (1986) 121.

    Google Scholar 

  38. W. Ooghe, F. Verbeek,Anal. Chim. Acta, 73 (1974) 87.

    Google Scholar 

  39. J.C. Van Loon, J.H. Galbraith, H.M. Aarden,Analyst, 96 (1971) 47.

    Google Scholar 

  40. R. Pribil,Talanta, 14 (1967) 619.

    Google Scholar 

  41. A.M. El-Kammer, M.A. Zayed, S.A. Amer,Chem. Geol., 24 (1979) 69.

    Google Scholar 

  42. J.A.C. Broekaert, F. Leis, K. Laqua,Spectrochim. Acta, 34B (1979) 73.

    Google Scholar 

  43. S. Nikdel, A. Massoumi, J.D. Winefordner,Microchem. J., 24 (1979) 1.

    Google Scholar 

  44. J.N. Walsh, F. Buckley, J. Barker,Chem. Geol., 33 (1981) 141.

    Google Scholar 

  45. I. Jarvis, K.E. Jarvis,Chem. Geol., 53 (1985) 335.

    Google Scholar 

  46. J.M. McArthur, J.N. Walsh,Chem. Geol., 47 (1984–5) 191.

    Google Scholar 

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Al-Merey, R., Bowen, H.J.M. Determination of the rare-earth elements in phosphate rocks using both inductively coupled plasma atomic emission spectrometry and instrumental neutron activation analysis. Journal of Radioanalytical and Nuclear Chemistry Letters 153, 221–234 (1991). https://doi.org/10.1007/BF02176877

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  • DOI: https://doi.org/10.1007/BF02176877

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