Abstract
Electrophilic aromatic astatination of equimolar mixtures of benzene and its derivatives has been studied in acid homogeneous medium. It has been quantitatively estimated, on the basis of the Hammett equation, how the properties of substitutients influence the yield of reaction products.
Similar content being viewed by others
References
R.D. Neirinckx, J.A. Myburgh, J.A. Smit, Proc. IAEA Conf. Radiopharmaceuticals and Labelled Compound, IAEA, Vienna, 1973, Vol. 2, p. 180.
A.T.M. Vaughan, J.H. Fremlin,Int. J. Applied Radiation and Isotopes, 28 /1977/ 595.
L. Vasaros, Yu.V. Norseyev, V.A. Khalkin, DAN USSR, 266 /1982/ 119.
L. Vasaros et al.:Radiochem. Radioanal. Lett., 54 /1982/ 239.
V.A. Palm, Osnovy kolychestvennoi teorii organicheskoi khimii, Khimia, L., 1977.
A.S. Dneproskii, T.I. Temnikova, Teoreticheskie osnovy organicheskoi khimii, Khimia, L., 1979.
K. Ingold, Teoreticheskie osnovy organicheskoi khimii /in Russian/, Mir, M., 1973, p. 246.
L. Vasaros et al., JINR, P12-81-643, Dubna, 1981.
V. Doberenz et al.,Radiochem. Radioanal. Lett., 52 /1982/ 119.
L. Vasaros et al., JINR, P6-81-16, Dubna, 1981.
L. Vasaros et al.,Radiochim. Acta, 26 /1979/ 171.
R.W. Taft, J. Phys. Chem., 64 /1960/ 1805.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Norseyev, Y.V., Nhan, D.D., Khalkin, V.A. et al. Rivals in astatination of equimolar mixtures of benzene and its derivatives. Journal of Radioanalytical and Nuclear Chemistry Letters 95, 137–144 (1985). https://doi.org/10.1007/BF02168274
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02168274