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Mössbauer study of iron in the grain boundary of aluminium

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Abstract

Iron was diffused into aluminium along grain boundaries and studied by Mössbauer spectroscopy. The Mössbauer spectrum of the investigated sample contained one doublet with isomer shift δ=0.360/5/ mm s−1 /relative to α-iron/ and quadrupole splitting Δ=0.84/l/ mm s−1. These results suggest that the iron atoms in the grain boundaries of aluminium have environment very similar to that which is present in amorphous iron /III/ oxides.

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Authors and Affiliations

  1. Laboratory of Nuclear Chemistry, L. Eötvös University, Puskin u. 11-13, H-1088, Budapest, Hungary

    Z. Homonnay, A. Vértes & E. Kuzmann

  2. Institute of Physics, Department of Solid State Physics, L. Kossuth University, P.O.Box 2, H-4010, Debrecen, Hungary

    D. L. Beke & I. Gödény

Authors
  1. Z. Homonnay
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  2. A. Vértes
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  3. D. L. Beke
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  4. I. Gödény
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  5. E. Kuzmann
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Homonnay, Z., Vértes, A., Beke, D.L. et al. Mössbauer study of iron in the grain boundary of aluminium. Journal of Radioanalytical and Nuclear Chemistry Letters 136, 371–377 (1989). https://doi.org/10.1007/BF02164729

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  • DOI: https://doi.org/10.1007/BF02164729

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