Abstract
Transport of yttrium(III) from nitrate medium through liquid membrane containing tri-n-octyl-phosphine oxide (TOPO) in n-dodecane, supported on a nucleoporous filter, into a strip solution with ethylenediaminetetraacetic acid (EDTA) has been studied. The kinetic dependences of transport were obtained and compared with a model, resulting in calculation of permeability coeffients and initial fluxes of yttrium. The influence of salting-out agent, initial metal and nitric acid concentrations in the feed, and of concentration of carrier in membrane are discussed.
Similar content being viewed by others
References
J.D. Way, R.D. Noble, T.M. Flynn, E.D. Sloan,J. Membr. Sci., 12 (1982) 239.
P.R. Danesi,Sep. Sci. Technol., 19 (1984–85) 857.
P.R. Danesi, Proc. ISEC'88, Vol. 3, pp. 27–29, Moscow, 1988.
R. Chiarizia, A. Castagnola, P.R. Danesi, E.P. Horwitz,J. Membr. Sci., 14 (1983) 1.
P.R. Danesi,J. Membr. Sci., 20 (1984) 231.
P.R. Danesi, Y.L. Reichley,J. Membr. Sci., 29 (1986) 195.
R. Kopunec, J.C. Benitez,J. Radioanal. Nucl. Chem., Articles, 151 (1991) 269.
V.V. Projaev, V.P. Kapranchik, A.A. Kopyrin, V.A. Polukev,Radiochimia, 31 (1989) 50.
M.R. El-Sourougy, S.M. Khalifa, E.E. Zaki, H.F. Aly, Proc. ISEC'88, Vol. 3, pp. 96, Moscow, 1988.
M. Sugiura, M. Kikkawa, S. Urita,J. Membr. Sci., 12 (1989) 47.
A. Alianz, Z. Moustapha,Ind. J. Chem., 3 (1965) 390.
R.A. Zingaro, J.C. Ivite,J. Inorg. Nucl. Chem., 12 (1960) 315.
A.I. Michalichenko,Radiochimia, 12 (1970) 594.
P.R. Danesi, C. Cianetti, E.P. Horwitz,Solv. Extr. Ion Exch., 1 (1983) 299.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kopunec, R., Manh, T.N. Carrier-mediated transport of yttrium(III) through a supported liquid membrane containing TOPO in n-dodecane. Journal of Radioanalytical and Nuclear Chemistry Letters 155, 311–323 (1991). https://doi.org/10.1007/BF02163878
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02163878